14.2. For binary solid liquid equibrium, show rigorously that the "freezing out" of the solvent from a metastable supercooled liquid phase results in an overall decrease in the Gibbs free energy. Remember that G/N u for a multicompo nent system.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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This problem is (14.2) from a book  "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

14.2. For binary solid liquid equibrium, show rigorously that the "freezing out" of the
solvent from a metastable supercooled liquid phase results in an overall
decrease in the Gibbs free energy. Remember that G/N
u for a multicompo
nent system.
Transcribed Image Text:14.2. For binary solid liquid equibrium, show rigorously that the "freezing out" of the solvent from a metastable supercooled liquid phase results in an overall decrease in the Gibbs free energy. Remember that G/N u for a multicompo nent system.
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