WS-3.3: Draw a detailed free energy diagram for the chlorination of benzene. Include and label the overall reactants, the overall products, the intermediate(s), the axis, and the transition state(s).
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- (a) • All hydrogen atoms are implied. • You do not have to consider stereochemistry. • Omit lone pairs and radical electrons from your answer. 3-ethyl-3-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. -8) O GA + H₂C * Cat CH₂ ? ChemDoodle Which process does this employ? 01. Hg(OAc)2, H₂O; 2. NaBH4 01. BH3; 2. H₂O2, NaOH OOSO4, H₂O2 YDraw the structure(s) of the major organic product(s) of the following reaction. os + **** H₂N-OH You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ChemDoodleⓇ Aqueous ethanol Ⓒ #[ ] در ▼n < SaDraw the structure of the organic product of the reaction between cyclohexene and OsO4, H₂O2. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. Separate multiple products using the + sign from the drop-down menu. • In cases where there is more than one answer, just draw one. ● MATIL ? Ⓡ ChemDoodle Sn [F
- 1. Draw the mechanism for the reaction between 1-butene and HBr. Then, draw an energy diagram for the same reaction. Be sure to label the axes, AH (or AG) for the reaction, the transition states, and the reactants, intermediates and product.Either the reactant (X) or the major organic product is missing from the equation below. Draw the missing compound. H3C CH3 CH,CHCHCHCH, Pd/C + H2 ČH3 • You do not have to consider stereochemistry. • In the case of a missing reactant, there may be more than one answer. If so, draw all possible reactants in separate windows. Separate structures with + signs from the drop-down menu. P. opy aste ChemDoodle (Previous NextDraw the structure(s) of the major organic product(s) of the following reaction. O N₂ HSO4 • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the sign from the drop-down menu. ● ? Cu₂O/Cu(NO3)2 in H₂O or H₂O, heat ChemDoodleⓇ ▼ #[ ] در
- The boiling points of several cyclic alkanes and ethers are listed in the table shown here. For small rings, there is a significant difference in boiling points between the cyclic alkane and the cyclic ether (e.g., – 76 °C vs. 10.7 °C), but for large rings, the boiling points are nearly the same (e.g., 80.7 °C vs. 88 °C). Explain. Сyclic Boiling Point (°C) Boiling Point (°C) Сyclic Alkane Ether -76 10.7 -13 50 49 66 80.7 88The compound below is treated with chlorine in the presence of light. CH3 CH3CHCH₂CH3 Draw the structure for the organic radical species produced by reaction of the compound with a chlorine atom. Assume reaction occurs at the weakest C-H bond. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. n [ ]# ?Using reactions, mechanisms, potential energy diagrams, labels, complete sentences, and the associated concepts, explain the following reaction rate trend for the hydrochlorination of alkenes (the addition of HCI). You may assume: 1) the alkenes are all the same higher energy; and, 2) the chloroalkane products are all the same energy; and, 3) the chloroalkane products are lower in energy than the starting alkenes (AGºrx is negative for each reaction).