Write the net ionic reactions and designate the nucleophile, substrate and the leaving group in the following reactions. CH3 CH3OCH2CH3 CH3CH2ONa + Nal a) 2CH3OH (CH3)3CCI b) (CH3)3 COCH3 CH3OH 2 + CI Br + 2NH3 c) NH2 + NH4Br
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in the following reactions.
CH3 CH3OCH2CH3
CH3CH2ONa + Nal
a)
2CH3OH (CH3)3CCI
b)
(CH3)3 COCH3 CH3OH 2 + CI
Br
+ 2NH3
c)
NH2
+ NH4Br"
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- The number of different monochlorinated constitutional isomers produced when each of the following undergo a uv light catalysed reaction with chlorine: Compound i: 2 Compound: ii: 1 Compound i: 3 Compound: ii: 4 Compound i: 4 Compound: ii: 2 Compound i: 5 Compound: ii: 1 Compound i: 6 Compound: ii: 3Consider the attached SN2 reaction. Question: What happens to the reaction rate in each of the following instances? [1] The leaving group is changed from Br− to I−; [2] The solvent is changed from acetone to CH3CH2OH; [3] The alkyl halide is changed from CH3(CH2)4Br to CH3CH2CH2CH(Br)CH3; [4] The concentration of −CN is increased by a factor of five; and [5] The concentrations of both the alkyl halide and −CN are increased by a factor of fiveAn electron-deficient carbon atom reacts with a nucleophile, symbolized as: Nu−. Define this ?
- 4. A CHEM 245 student wants to synthesize some ethylene glycol to use as antifreeze in his radiator this winter. He proposes the following reaction to his instructor, who quickly explains that this reaction won't work as proposed due to the student's choice of reagent. 1) NaH 2) H20 OH Но a) Why can't sodium hydride (NaH) be used as the nucleophile in the reaction above? b) Propose an alternate reagent that COULD be used with the ethylene oxide to successfully give the desired ethylene glycol product.Carbonic anhydrase, an enzyme that converts carbon dioxide and water to carbonic acid as shown below, functions in the blood at an optimum pH of 7.0-7.5. Which of the following will lower the rate of carbonic anhydrase- catalyzed reaction? CO2 + H2O Carbonic anhydrase H₂CO3 O increasing the concentration of carbon dioxide O running the reaction at 4 °C carrying out the reaction at pH 7.2 O adding more carbonic anhydraseWhich of the following compounds precipitates during a positive test for SN1 reactivity of an alkyl halide? A positive test does not give a precipitate. alcohol complexed to Ag AgBr or AgCl Ag (H₂O) elemental mercury elemental silver alkyl nitrates
- Draw the structure(s) of the major organic product(s), for each of the following reactions.Which carbon will attack the alkyl halide (methyl iodide) in the major organic product of the following substitution reaction? B H₂ CH3 A D 1) LDA, THF 2) CHẠI C A B ں 000 DWhat reagents are needed to carry out this reaction? CH;CH,CH2CCH PCC in methylene chloride Sia2BH and then basic hydrogen peroxide Aqueous acid and mercury sulfate MCPBA and then Swern Oxidation Question 10 What is the intermediate that forms during this reaction? CH;CH,CH,CCH O an enol an epoxide an alkoxide a carbanion
- Draw the structure(s) of the major organic product(s), including counterions, of the following reaction. HBr + NH₂Which pair of reactants is most likely to undergo an SN2 reaction? CH3CO₂Na + (CH3)₂CHCH₂CH₂CH₂Br at 22°C CH3CO₂H + CH3CH₂CH₂CBr(CH3)2 at 20°C CH3NH2 + CH3CH₂C(CH3)BrCH₂CH3 at 70°C (CH3)3CONa + (CH3)2CBrCH(CH3)CH3 at 28°CWhat interactions in the products are consistent across all four reactions?
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