Write the net ionic reactions and designate the nucleophile, substrate and the leaving group in the following reactions. CH3 CH3OCH2CH3 CH3CH2ONa + Nal a) 2CH3OH (CH3)3CCI b) (CH3)3 COCH3 CH3OH 2 + CI Br + 2NH3 c) NH2 + NH4Br
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- For the given Sy2 reaction, draw the organic and inorganic products of the reaction, and identify the nucleophile, substrate, and leaving group. Include wedge-and-dash bonds and draw hydrogen on a stereocenter. :CEN Organic product Inorganic product + Draw the organic product. Draw the inorganic product. Incorrect2) Organocuprates are important nucleophile in organic chemistry. They are usually generated from Grignard reagents (equation below). Draw a picture of the transition state for this reaction and why is the product formation favorable. CuR MgBrl Cul + +Trimethyllead hydride, (CH3)3PbH, can react with methyl bromide (CH3Br) in a homolytic dissociation reaction. What will the lead-containing product be? (CH3)2Pb PbBr2 (CH3)3PbBr Pb metal
- The number of different monochlorinated constitutional isomers produced when each of the following undergo a uv light catalysed reaction with chlorine: Compound i: 2 Compound: ii: 1 Compound i: 3 Compound: ii: 4 Compound i: 4 Compound: ii: 2 Compound i: 5 Compound: ii: 1 Compound i: 6 Compound: ii: 3Alcohols are acidic in nature. Therefore, a strong base can abstract the acidic hydrogen atom of the alcohol in a process known as deprotonation. The alcohol forms an alkoxide ion by losing the proton attached to the oxygen atom of the hydroxyl ( -OH) group. The alkoxide formed can act as a base or a nucleophile depending on the substrate and reaction conditions. However, not all bases can abstract the acidic proton of alcohols and not all alcohols easily lose the proton. Deprotonation depends on the strength of the base and the acidity of the alcohol. Strong bases, such as NaNH2, can easily abstract a proton from almost all alcohols. Likewise, more acidic alcohols lose a proton more easily. Determine which of the following reactions would undergo deprotonation based on the strength of the base and the acidity of the alcohol. Check all that apply. ► View Available Hint(s) CH3CH,OH + NH3 →CH,CH,O-NH CH3 CH3 H3C-C-H+NH3 → H3 C-C-H OH O-NH CH3CH2OH + NaNH, → CH3CH,O-Na* + NH3 CHC12 Cl₂…Identify the leaving group for a potential elimination of the following compounds. Compare the leaving group activities for A and K. Which of the following compounds cannot be subjected to elimination? Explain.
- Do not give handwriting solution.The SN2 type reaction will end up with the substitution 2903 the at the reaction center of the reaction. 903 182903 SEY 9037Consider the attached SN2 reaction. Question: What happens to the reaction rate in each of the following instances? [1] The leaving group is changed from Br− to I−; [2] The solvent is changed from acetone to CH3CH2OH; [3] The alkyl halide is changed from CH3(CH2)4Br to CH3CH2CH2CH(Br)CH3; [4] The concentration of −CN is increased by a factor of five; and [5] The concentrations of both the alkyl halide and −CN are increased by a factor of five
- An electron-deficient carbon atom reacts with a nucleophile, symbolized as: Nu−. Define this ?Which is the oxaphosphetane intermediate? Br Ph3P-CH,CH,Ph NaH THF Ph3P-CHCH,Ph Reaction intermediate C14H18 ketone ylideFill in the missing intermediates and reagents in the scheme below 1) BH3 THF 2) NaOH/H2O2 OH H2CrO4