Which of the following are intermediates in the mechanism for the reaction shown? (product intentionally not shown) Br I. I. only II. only II. and III. I. and III. (+) Br₂ CH3SH II. Br I III.
Which of the following are intermediates in the mechanism for the reaction shown? (product intentionally not shown) Br I. I. only II. only II. and III. I. and III. (+) Br₂ CH3SH II. Br I III.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Title:** Identifying Reaction Intermediates
**Question:** Which of the following are intermediates in the mechanism for the reaction shown? (Product intentionally not shown)
**Reaction:**
- **Reactants:** An alkene reacting with Br₂ in the presence of CH₃SH.
- **Process:** The alkene undergoes a reaction with bromine and a thiol (CH₃SH).
**Potential Intermediates:**
**Structure I:**
- A bromonium ion intermediate.
- Features a three-membered ring with a positively charged bromine atom.
**Structure II:**
- A carbocation intermediate.
- Has a positively charged carbon atom bonded to a sulfur atom with a negative charge (S⁻).
**Structure III:**
- A stabilized carbocation intermediate.
- Contains both a bromine atom and a sulfur atom, with a positive charge on the sulfur.
**Options for Selection:**
- ○ I. only
- ○ II. only
- ○ II. and III.
- ○ I. and III.
Carefully analyze the types of intermediates typically involved in halogenation reactions of alkenes and the possible role of thiol in stabilizing intermediate structures.
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