+ CI a. Draw the structure of the tetrahedral intermediate INITIALLY FORMED in the reaction shown.

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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b. Draw the structures of the final acyl transfer products obtained.

- You do not have to consider stereochemistry.
- Draw organic products only.
- Draw the neutral form of the products; no charges.
- Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
- Separate multiple products using the + sign from the drop-down menu.

### ChemDoodle Toolbar:
The image displays a blank canvas with a toolbar containing various drawing tools ideal for chemical structure visualization. These tools include:

- Pen and arrow tools for drawing structures and reactions.
- Templates for common structures such as benzene rings and cyclohexane.
- Options to add text, erase, and adjust drawings.
- A zoom feature and options to copy and paste structures.
- Drop-down menu to add more sketchers or separate products.
- A ChemDoodle logo indicating the software used.

This interface allows for detailed chemical drawing and is commonly used in educational settings for visualizing organic chemistry reactions and products.
Transcribed Image Text:b. Draw the structures of the final acyl transfer products obtained. - You do not have to consider stereochemistry. - Draw organic products only. - Draw the neutral form of the products; no charges. - Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. - Separate multiple products using the + sign from the drop-down menu. ### ChemDoodle Toolbar: The image displays a blank canvas with a toolbar containing various drawing tools ideal for chemical structure visualization. These tools include: - Pen and arrow tools for drawing structures and reactions. - Templates for common structures such as benzene rings and cyclohexane. - Options to add text, erase, and adjust drawings. - A zoom feature and options to copy and paste structures. - Drop-down menu to add more sketchers or separate products. - A ChemDoodle logo indicating the software used. This interface allows for detailed chemical drawing and is commonly used in educational settings for visualizing organic chemistry reactions and products.
### Understanding Tetrahedral Intermediates in Reactions

#### Reaction Overview:

In the reaction shown, we have two reactants:

1. **Reactant 1**: An acyl chloride with a benzene ring (aromatic group) bonded to a carbonyl group \((C=O)\) and a chlorine atom (Cl) attached to the same carbon atom.

2. **Reactant 2**: A cyclopentanol, which is a five-membered carbon ring structure with an alcohol group \((OH)\).

The arrow indicates a reaction is occurring between these two compounds.

#### Task Details:

- **Objective**: Draw the structure of the tetrahedral intermediate initially formed.
- **Guidelines**:
  - Ignore stereochemistry in the drawing.
  - Avoid including counter-ions, such as \(\text{Na}^+\) or \(\text{I}^-\).
  - If multiple intermediates are possible, depicting any one of them suffices.

#### Steps for Drawing the Intermediate:

1. **Nucleophilic Attack**: 
    - The lone pair on the oxygen of the cyclopentanol hydroxyl group attacks the electrophilic carbonyl carbon in the acyl chloride, leading to formation of the tetrahedral intermediate.

2. **Formation of the Tetrahedral Intermediate**:
    - This attack results in the breaking of the \(C=O\) double bond, forming an alkoxide.
    - The chlorine atom (Cl) remains attached to the carbon during this step.

3. **Structure Considerations**:
    - The central carbon now forms four single bonds, turning the planar group into a tetrahedral geometry.
    - Ensure the depiction includes all bonds that result from this transformation.

#### Editor Usage for Drawing:

- Utilize drawing tools to sketch the reaction mechanism.
- Use the bond and atom tools to accurately represent the tetrahedral configuration.

This step is key for understanding acyl transfer reactions commonly encountered in organic chemistry and biochemistry.
Transcribed Image Text:### Understanding Tetrahedral Intermediates in Reactions #### Reaction Overview: In the reaction shown, we have two reactants: 1. **Reactant 1**: An acyl chloride with a benzene ring (aromatic group) bonded to a carbonyl group \((C=O)\) and a chlorine atom (Cl) attached to the same carbon atom. 2. **Reactant 2**: A cyclopentanol, which is a five-membered carbon ring structure with an alcohol group \((OH)\). The arrow indicates a reaction is occurring between these two compounds. #### Task Details: - **Objective**: Draw the structure of the tetrahedral intermediate initially formed. - **Guidelines**: - Ignore stereochemistry in the drawing. - Avoid including counter-ions, such as \(\text{Na}^+\) or \(\text{I}^-\). - If multiple intermediates are possible, depicting any one of them suffices. #### Steps for Drawing the Intermediate: 1. **Nucleophilic Attack**: - The lone pair on the oxygen of the cyclopentanol hydroxyl group attacks the electrophilic carbonyl carbon in the acyl chloride, leading to formation of the tetrahedral intermediate. 2. **Formation of the Tetrahedral Intermediate**: - This attack results in the breaking of the \(C=O\) double bond, forming an alkoxide. - The chlorine atom (Cl) remains attached to the carbon during this step. 3. **Structure Considerations**: - The central carbon now forms four single bonds, turning the planar group into a tetrahedral geometry. - Ensure the depiction includes all bonds that result from this transformation. #### Editor Usage for Drawing: - Utilize drawing tools to sketch the reaction mechanism. - Use the bond and atom tools to accurately represent the tetrahedral configuration. This step is key for understanding acyl transfer reactions commonly encountered in organic chemistry and biochemistry.
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