When the oxide of generic metal M is heated at 25.0 °C, a negligible amount of M is produced. MO,(s) = M(s) + 0,(g) kJ AG° = 287.4- mol When this reaction is coupled to the conversion of graphite to carbon dioxide, it becomes spontaneous. What is the chemical equation of this coupled process? Show that the reaction is in equilibrium. Include physical states and represent graphite as C(s). chemical equation: What is the thermodynamic equilbrium constant for the coupled reaction? K =

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**Equilibrium and Thermodynamics of Coupled Reactions**

**Problem Overview:**
When the oxide of generic metal M is heated at 25.0 °C, a negligible amount of M is produced.

\[ \text{MO}_2 (s) \rightleftharpoons \text{M} (s) + \text{O}_2 (g) \]
\[ \Delta G^\circ = 287.4 \, \frac{\text{kJ}}{\text{mol}} \]

When this reaction is coupled to the conversion of graphite to carbon dioxide, it becomes spontaneous.

**Question 1: Chemical Equation of the Coupled Process**
What is the chemical equation of this coupled process? Show that the reaction is in equilibrium. Include physical states and represent graphite as C(s).

**Answer:**
\[ \text{chemical equation:} \]
\[ \boxed{\text{MO}_2 (s) + \text{C} (s) \rightleftharpoons \text{M} (s) + \text{CO}_2 (g)} \]

**Question 2: Thermodynamic Equilibrium Constant**
What is the thermodynamic equilibrium constant for the coupled reaction?

**Answer:**
\[ K = \boxed{} \]

**Explanation:**
When exploring the equilibrium and thermodynamics of reactions, combining exergonic (energy-releasing) and endergonic (energy-absorbing) reactions can drive the overall process to be spontaneous. The given reaction demonstrates this principle by coupling the metal oxide decomposition with graphite oxidation, thus enabling the reaction to proceed spontaneously. The problem aims to showcase these thermodynamic principles in action.
Transcribed Image Text:**Equilibrium and Thermodynamics of Coupled Reactions** **Problem Overview:** When the oxide of generic metal M is heated at 25.0 °C, a negligible amount of M is produced. \[ \text{MO}_2 (s) \rightleftharpoons \text{M} (s) + \text{O}_2 (g) \] \[ \Delta G^\circ = 287.4 \, \frac{\text{kJ}}{\text{mol}} \] When this reaction is coupled to the conversion of graphite to carbon dioxide, it becomes spontaneous. **Question 1: Chemical Equation of the Coupled Process** What is the chemical equation of this coupled process? Show that the reaction is in equilibrium. Include physical states and represent graphite as C(s). **Answer:** \[ \text{chemical equation:} \] \[ \boxed{\text{MO}_2 (s) + \text{C} (s) \rightleftharpoons \text{M} (s) + \text{CO}_2 (g)} \] **Question 2: Thermodynamic Equilibrium Constant** What is the thermodynamic equilibrium constant for the coupled reaction? **Answer:** \[ K = \boxed{} \] **Explanation:** When exploring the equilibrium and thermodynamics of reactions, combining exergonic (energy-releasing) and endergonic (energy-absorbing) reactions can drive the overall process to be spontaneous. The given reaction demonstrates this principle by coupling the metal oxide decomposition with graphite oxidation, thus enabling the reaction to proceed spontaneously. The problem aims to showcase these thermodynamic principles in action.
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