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1. Given the following reactions and data, use addition (similar to Hess's Law) to calculate AG° for H3PO4 (s). (Hint: The overall reaction is for the formation of 1 mol of H3PO4 (s) from elements in their natural state (elemental phosphorus is P4 (s)). PA () + 5 02@ → P,O10 (5) AG; - 2698 kJ P,O10 (9) + 6 H0 m → 4 H3P04 () H2 ( + ½ 02 (2) → H;O @ AG° = – 396 kJ - 228.6 kJ AG; : AG vap H,O 0 → H2O @ 8.6 kJ Required work: * rewrite the reactions above in the correct direction, using multipliers to change coefficients and modify AG° values if necessary * show that after cancelling, the sum of your reactions gives the desired overall reaction Write the goal equation first?

1. Given the following reactions and data, use addition (similar to Hess's Law) to calculate AG° for H3PO4 (s). (Hint: The overall reaction is for the formation of 1 mol of H3PO4 (s) from elements in their natural state (elemental phosphorus is P4 (s)). PA () + 5 02@ → P,O10 (5) AG; - 2698 kJ P,O10 (9) + 6 H0 m → 4 H3P04 () H2 ( + ½ 02 (2) → H;O @ AG° = – 396 kJ - 228.6 kJ AG; : AG vap H,O 0 → H2O @ 8.6 kJ Required work: * rewrite the reactions above in the correct direction, using multipliers to change coefficients and modify AG° values if necessary * show that after cancelling, the sum of your reactions gives the desired overall reaction Write the goal equation first?

Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter8: Thermochemistry
Section: Chapter Questions
Problem 87QAP: The thermite reaction was once used to weld rails: 2Al(s)+Fe2O3(s)Al2O3(s)+2Fe(s)(a) Using heat of...
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1. Given the following reactions and data, use addition (similar to Hess's Law) to calculate AG° for H3PO4 (s). (Hint: The overall reaction is for the formation of 1 mol of H3PO4 (s) from elements in their natural state (elemental phosphorus is P4 (s)). PA () + 5 02@ → P,O10 (5) AG; - 2698 kJ P,O10 (9) + 6 H0 m → 4 H3P04 () H2 ( + ½ 02 (2) → H;O @ AG° = – 396 kJ - 228.6 kJ AG; : AG vap H,O 0 → H2O @ 8.6 kJ Required work: * rewrite the reactions above in the correct direction, using multipliers to change coefficients and modify AG° values if necessary * show that after cancelling, the sum of your reactions gives the desired overall reaction Write the goal equation first?
Transcribed Image Text:1. Given the following reactions and data, use addition (similar to Hess's Law) to calculate AG° for H3PO4 (s). (Hint: The overall reaction is for the formation of 1 mol of H3PO4 (s) from elements in their natural state (elemental phosphorus is P4 (s)). PA () + 5 02@ → P,O10 (5) AG; - 2698 kJ P,O10 (9) + 6 H0 m → 4 H3P04 () H2 ( + ½ 02 (2) → H;O @ AG° = – 396 kJ - 228.6 kJ AG; : AG vap H,O 0 → H2O @ 8.6 kJ Required work: * rewrite the reactions above in the correct direction, using multipliers to change coefficients and modify AG° values if necessary * show that after cancelling, the sum of your reactions gives the desired overall reaction Write the goal equation first?
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