When a concentrated urea solution is stored it slowly condenses to biuret by the following elementary reaction: 2 NH2-CO-NH2 --> NH2-CO-NH-CO-NH2 + NH3 To study the rate of condensation a sample of urea (C = 20 mol/liter) is stored at 100°C and after 7 hr 40 min we find that 1 mol% has turned into biuret. Find the rate equation for this condensation reaction

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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When a concentrated urea solution is stored it slowly condenses to biuret by the following elementary reaction:

2 NH2-CO-NH2 --> NH2-CO-NH-CO-NH2 + NH3

To study the rate of condensation a sample of urea (C = 20 mol/liter) is stored at 100°C and after 7 hr 40 min we find that 1 mol% has turned into biuret. Find the rate equation for this condensation reaction

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