What will be the major product of the following reaction? + Br2 ? H2O

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question:**
What will be the major product of the following reaction?

Reactant: 

- A hydrocarbon with a carbon-carbon double bond.

Reaction conditions:

- Reacting with \( \text{Br}_2 \) in the presence of \( \text{H}_2\text{O} \).

**Options:**

1. **Option A:**
   - The structure shows a hydroxyl group (OH) and a bromine atom (Br) attached to adjacent carbon atoms, with the OH on the more substituted carbon.

2. **Option B:**
   - The structure shows a bromine atom (Br) and a hydroxyl group (OH) attached next to each other, with the Br on the more substituted carbon.

3. **Option C:**
   - The structure displays a hydroxyl group (OH) and a bromine atom (Br) attached to adjacent carbon atoms, with OH on the less substituted carbon.

4. **Option D:**
   - The structure includes a bromine atom (Br) and a hydroxyl group (OH) arranged on adjacent carbon atoms, with the Br attached to the less substituted carbon.

5. **Option E:**
   - The structure exhibits a bromine atom (Br) and a hydroxyl group (OH) attached to adjacent carbon atoms in a configuration similar to Option B.

**Explanation:**

In reactions involving halogens and water, such as \( \text{Br}_2 \) with \( \text{H}_2\text{O} \), halohydrins are typically formed. The hydroxyl group will usually attach to the more substituted carbon (Markovnikov addition), while the halogen attaches to the less substituted carbon due to the generation of a cyclic bromonium ion intermediate.
Transcribed Image Text:**Question:** What will be the major product of the following reaction? Reactant: - A hydrocarbon with a carbon-carbon double bond. Reaction conditions: - Reacting with \( \text{Br}_2 \) in the presence of \( \text{H}_2\text{O} \). **Options:** 1. **Option A:** - The structure shows a hydroxyl group (OH) and a bromine atom (Br) attached to adjacent carbon atoms, with the OH on the more substituted carbon. 2. **Option B:** - The structure shows a bromine atom (Br) and a hydroxyl group (OH) attached next to each other, with the Br on the more substituted carbon. 3. **Option C:** - The structure displays a hydroxyl group (OH) and a bromine atom (Br) attached to adjacent carbon atoms, with OH on the less substituted carbon. 4. **Option D:** - The structure includes a bromine atom (Br) and a hydroxyl group (OH) arranged on adjacent carbon atoms, with the Br attached to the less substituted carbon. 5. **Option E:** - The structure exhibits a bromine atom (Br) and a hydroxyl group (OH) attached to adjacent carbon atoms in a configuration similar to Option B. **Explanation:** In reactions involving halogens and water, such as \( \text{Br}_2 \) with \( \text{H}_2\text{O} \), halohydrins are typically formed. The hydroxyl group will usually attach to the more substituted carbon (Markovnikov addition), while the halogen attaches to the less substituted carbon due to the generation of a cyclic bromonium ion intermediate.
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