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- Out of acid chlorides (least stable), anhydrides, esters, and amides (most stable). True or false Acid chlorides would be the most reactive to hydrolysis and Amides would be the least reactiveThe cyang group is often considered to be more stable than esters or even amides when reacting with a nucleophile. Please list at least two reasons why -CN is more stable than any other carboxylic acid derivativeArrange the following functional groups according to their DECREASING reactivity with nucleophiles. [esters, carboxylic acids, acyl halides, amides, anhydrides]
- Explain why a proton can be removed from the 'alpha-carbon of N,N-dimethylethanamide but not from the alpha-carbon of either N-methylethanamide or ethanamide.Aldol condensation- Synthesis of Dibenzalacetone reaction What is this reaction classified as?a) Put these three common types of carbonyl compound in order of decreasing reactivity ester amide acid chloride b) For the least reactive, show the interconversion to its other resonance form: How does this electron delocalisation make it stable? c) For the most reactive, draw the mechanism of its undergoing hydrolysis (reaction with H2O): Why makes this type of carbonyl so reactive to nucleophiles?
- We saw that it is necessary to use excess amine in the reaction of an acyl chloride with an amine. Explain why it is not necessary to use excess alcohol in the reaction of an acyl chloride with an alcohol.What is difference between the acetoacetic and malonic ester syntheses? Provide an example of each, including all intermediates..Which of the following best represents a mechanistic step in the acid-catalyzed hydrolysis of acetonitrile? А) НС —СEN: Н-ӧ: Н В) НС —СN-H Н-ӧ: н С) НС —СN: н ӧ: D) H3C-C=N: Н-ӧ: н
- Two reactions occur when sodium hydroxide is added to methyl salicylate. One is immediate and one only occurs with reflux over time. What type of reaction occurs immediately and with which functional group on methyl salicylate does it react? What type of reaction occurs with reflux over time and with which functional group on methyl salicylate does it react?Provide a retrosynthetic analysis and forward synthesis for the compound shown below. H- and any other reagent of one carbon or less.I need help please
