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- The reaction that occurs when the benzaldehyde you have is reacted in a basic environment is called the Cannizzaro reaction, and when it is reacted with cyanide, it is called benzoin production. Write down the reaction mechanisms of these reactions and explain why.Explain the reaction for the formation of acetal and hemiacetal. Explain why N,N-disubstituted amide is less acidic than ester. Why only methyl ketone do undergoes haloform reaction. LDA is the base of choice for carbonyl compound to completely convert into enolate. Why?If possible would you be able to solve and explain these questions?
- The cyang group is often considered to be more stable than esters or even amides when reacting with a nucleophile. Please list at least two reasons why -CN is more stable than any other carboxylic acid derivative9) a) Diagram the acid (H3O+) catalyzed enolizaton of acetaldehyde. . b) Diagram the base (OH-) catalyzed formation of cyclopentanone from its enol form.Aldol Condensation- Synthesis of Dibenzalacetone The protocol says that, after adding in all the reactants, stir for an additional 15 minutes. A student swirled for only 8 minutes and then, correctly, stopped and proceeded with isolating the product. What did the student do that gave such confidence and accuracy?
- Aldol condensation- Synthesis of Dibenzalacetone reaction What is this reaction classified as?show why and explain how biphenyl is the major product in the synthesis of triphenylmethanola) Put these three common types of carbonyl compound in order of decreasing reactivity ester amide acid chloride b) For the least reactive, show the interconversion to its other resonance form: How does this electron delocalisation make it stable? c) For the most reactive, draw the mechanism of its undergoing hydrolysis (reaction with H2O): Why makes this type of carbonyl so reactive to nucleophiles?
- What is difference between the acetoacetic and malonic ester syntheses? Provide an example of each, including all intermediates..a) Write out the first 3 steps only(to the tetrahedral intermediate shown) in the 6-step arrow pushing mechanism showing how ethyl propanoate is hydrolyzed in acid to form propanoic acidand ethanol. b) NaOH/H2O also serveto hydrolyze an ester; briefly explain why NaOH/H2Ois generally preferable.Which of the following best represents a mechanistic step in the acid-catalyzed hydrolysis of acetonitrile? А) НС —СEN: Н-ӧ: Н В) НС —СN-H Н-ӧ: н С) НС —СN: н ӧ: D) H3C-C=N: Н-ӧ: н
