What is the numerical value of the molecular partition function of a heteronuclear diatomic molecule given the following conditions: (i) the characteristic length is 10 nm and the volume in which the molecules are free to move is a cube with sides of 1 mm each. (ii) Only the first four rotational levels are accessible, but for some odd reason [to keep things simple] each state in each of those levels is equally populated. (iii) all molecules are in the ground vibrational state; (iv) the molecule has a triplet electronic ground level, like 02.
What is the numerical value of the molecular partition function of a heteronuclear diatomic molecule given the following conditions: (i) the characteristic length is 10 nm and the volume in which the molecules are free to move is a cube with sides of 1 mm each. (ii) Only the first four rotational levels are accessible, but for some odd reason [to keep things simple] each state in each of those levels is equally populated. (iii) all molecules are in the ground vibrational state; (iv) the molecule has a triplet electronic ground level, like 02.
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 13P
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![What is the numerical value of the molecular
partition function of a heteronuclear diatomic
molecule given the following conditions:
(i) the characteristic length is 10 nm and the
volume in which the molecules are free to
move is a cube with sides of 1 mm each.
(ii) Only the first four rotational levels are
accessible, but for some odd reason [to keep
things simple] each state in each of those
levels is equally populated.
(iii) all molecules are in the ground vibrational
state;
(iv) the molecule has a triplet electronic
ground level, like 02.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbee58e0c-ec94-4fd5-800f-37f090c43735%2F422ba719-c891-4658-aec9-05787f168696%2Fg65faa_processed.jpeg&w=3840&q=75)
Transcribed Image Text:What is the numerical value of the molecular
partition function of a heteronuclear diatomic
molecule given the following conditions:
(i) the characteristic length is 10 nm and the
volume in which the molecules are free to
move is a cube with sides of 1 mm each.
(ii) Only the first four rotational levels are
accessible, but for some odd reason [to keep
things simple] each state in each of those
levels is equally populated.
(iii) all molecules are in the ground vibrational
state;
(iv) the molecule has a triplet electronic
ground level, like 02.
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