We know that trivalent cations (Cr3+, Mn3+, V3+) with a large difference between octahedral and tetrahedral EECC, form exclusively normal spinels. Bivalent cations (Ni2+ and Cu2+) with high EECC, form inverse spinels. Is this statement correct?

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Chapter1: Chemical Foundations
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We know that trivalent cations (Cr3+, Mn3+, V3+) with a large difference between octahedral and tetrahedral EECC, form exclusively normal spinels. Bivalent cations (Ni2+ and Cu2+) with high EECC, form inverse spinels. Is this statement correct?

 

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