Answered: Radii were reported as follows: Ti4+ =…

Chemistry & Chemical Reactivity

9th Edition

ISBN:9781133949640

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter21: The Chemistry Of The Main Group Elements

Section: Chapter Questions

Problem 43PS

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Question

Radii were reported as follows: Ti4+ = 60 pm; O2‒ = 140 pm. Based on this, tell as much as you
can about the expected structure of TiO2 – provide the hole type for the cation, the cell lattice,
and the coordination numbers for both cation and anion.

Expert Solution

Step 1

TiO₂ has a tetragonal geometry.

TiO2 is a fluorite structure that means AB₂type formula.

Coordination number of Ti⁴⁺ is 6

Coordination number of O^2- is 3

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