Valence Shell Bonding Nonbonding Approx. Bond Molecule or Lewis Electron Electron Electron VSEPR Geometric Molecular Ion Structure Pairs Pairs Pairs Formula Angle Shape 1. CH, 4 4 AX, 109.5° tetrahedral H H:C:H 1. Complete the table (as outlined above) for the following molecules/molecular ions, all of which obey the Lewis octet rule. Complete those that are assigned by your laboratory instructor. j. SiF, k. H,S

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## Determining Molecular Geometry Using the VSEPR Model

Understanding the geometry of molecules is crucial for a deeper insight into their chemical properties and behavior. Here, we explore the Valence Shell Electron Pair Repulsion (VSEPR) model with an example and an exercise for different molecules/molecular ions:

### Example: Methane (CH₄)

| Molecule or Molecular Ion | Lewis Structure | Valence Shell Electron Pairs | Bonding Electron Pairs | Nonbonding Electron Pairs | VSEPR Formula | Approx. Bond Angle | Geometric Shape |
|----------------------------|------------------|-----------------------------|------------------------|---------------------------|---------------|---------------------|-----------------|
| **1. CH₄**                         | ![Lewis structure of CH4](ch4_lewis.png)  | 4                             | 4                      | 0                           | AX₄                      | 109.5°                    | Tetrahedral           |

**Explanation:**
- **Lewis Structure:** The central carbon atom forms four single bonds with hydrogen atoms, with no lone pairs on the carbon.
- **Valence Shell Electron Pairs:** The carbon atom in CH₄ has four valence electron pairs.
- **Bonding Electron Pairs:** All four pairs are involved in bonding (with hydrogen atoms).
- **Nonbonding Electron Pairs:** There are no lone pairs of electrons on the central atom.
- **VSEPR Formula:** AX₄ (where A represents the central atom, and X₄ represents four bonding pairs).
- **Approx. Bond Angle:** The bond angles are approximately 109.5°.
- **Geometric Shape:** The geometric shape is tetrahedral.

### Exercise:

Complete the table (as outlined above) for the following molecules/molecular ions, all of which obey the Lewis octet rule. Complete those that are assigned by your laboratory instructor.

1. **SiF₄**
2. **H₂S**
3. **NH₂⁻**

By analyzing these molecules, you will gain practice in applying the VSEPR model to predict molecular geometries based on the Lewis structures and valence shell electron pairs.
Transcribed Image Text:## Determining Molecular Geometry Using the VSEPR Model Understanding the geometry of molecules is crucial for a deeper insight into their chemical properties and behavior. Here, we explore the Valence Shell Electron Pair Repulsion (VSEPR) model with an example and an exercise for different molecules/molecular ions: ### Example: Methane (CH₄) | Molecule or Molecular Ion | Lewis Structure | Valence Shell Electron Pairs | Bonding Electron Pairs | Nonbonding Electron Pairs | VSEPR Formula | Approx. Bond Angle | Geometric Shape | |----------------------------|------------------|-----------------------------|------------------------|---------------------------|---------------|---------------------|-----------------| | **1. CH₄** | ![Lewis structure of CH4](ch4_lewis.png) | 4 | 4 | 0 | AX₄ | 109.5° | Tetrahedral | **Explanation:** - **Lewis Structure:** The central carbon atom forms four single bonds with hydrogen atoms, with no lone pairs on the carbon. - **Valence Shell Electron Pairs:** The carbon atom in CH₄ has four valence electron pairs. - **Bonding Electron Pairs:** All four pairs are involved in bonding (with hydrogen atoms). - **Nonbonding Electron Pairs:** There are no lone pairs of electrons on the central atom. - **VSEPR Formula:** AX₄ (where A represents the central atom, and X₄ represents four bonding pairs). - **Approx. Bond Angle:** The bond angles are approximately 109.5°. - **Geometric Shape:** The geometric shape is tetrahedral. ### Exercise: Complete the table (as outlined above) for the following molecules/molecular ions, all of which obey the Lewis octet rule. Complete those that are assigned by your laboratory instructor. 1. **SiF₄** 2. **H₂S** 3. **NH₂⁻** By analyzing these molecules, you will gain practice in applying the VSEPR model to predict molecular geometries based on the Lewis structures and valence shell electron pairs.
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