Using only the information in the pK table below, write an estimated pK value for each labeled H in the two structures below. For example, if the pK, value of the H labeled a has an estimated value of 50, write 50 in the first box of the answer table and so on. hor :0: H d :0: 0: H b pka 0 b 0 0 0 H a с d X acid CH, 4 NH3 HC=CH II CH CCH3 H₂O || CH,CNH, pK 50 35 25 19 16 15 ? A olo Ar
Using only the information in the pK table below, write an estimated pK value for each labeled H in the two structures below. For example, if the pK, value of the H labeled a has an estimated value of 50, write 50 in the first box of the answer table and so on. hor :0: H d :0: 0: H b pka 0 b 0 0 0 H a с d X acid CH, 4 NH3 HC=CH II CH CCH3 H₂O || CH,CNH, pK 50 35 25 19 16 15 ? A olo Ar
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![**Instructions:**
Using only the information in the pKₐ table below, write an estimated pKₐ value for each labeled H in the two structures below. For example, if the pKₐ value of the H labeled *a* has an estimated value of 50, write 50 in the first box of the answer table and so on.
**Structures:**
- **Structure 1:**
- Proton labeled *a* attached to a nitrogen.
- Proton labeled *b* attached to an oxygen within a furan ring.
- **Structure 2:**
- Proton labeled *c* attached to an oxygen connected to a carbon ring.
- Proton labeled *d* attached to an oxygen at a hydroxyl group.
**Answer Table:**
| H | pKₐ |
|---|-----|
| a | |
| b | |
| c | |
| d | |
**pKₐ Reference Table:**
| Acid | pKₐ |
|-------------|-----|
| CH₄ | 50 |
| NH₃ | 35 |
| HC≡CH | 25 |
| CH₃C≡CH | 19 |
| H₂O | 16 |
| CH₃CNH₂ | 15 |
**Task:**
Estimate the pKₐ values based on the protons’ environments in each structure using the reference table provided.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F70c6702f-1254-4f2b-ba5a-ac93276291c3%2Ff3b0c4f8-2a93-40f5-82cb-020b66e451ef%2F250mk7a_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Instructions:**
Using only the information in the pKₐ table below, write an estimated pKₐ value for each labeled H in the two structures below. For example, if the pKₐ value of the H labeled *a* has an estimated value of 50, write 50 in the first box of the answer table and so on.
**Structures:**
- **Structure 1:**
- Proton labeled *a* attached to a nitrogen.
- Proton labeled *b* attached to an oxygen within a furan ring.
- **Structure 2:**
- Proton labeled *c* attached to an oxygen connected to a carbon ring.
- Proton labeled *d* attached to an oxygen at a hydroxyl group.
**Answer Table:**
| H | pKₐ |
|---|-----|
| a | |
| b | |
| c | |
| d | |
**pKₐ Reference Table:**
| Acid | pKₐ |
|-------------|-----|
| CH₄ | 50 |
| NH₃ | 35 |
| HC≡CH | 25 |
| CH₃C≡CH | 19 |
| H₂O | 16 |
| CH₃CNH₂ | 15 |
**Task:**
Estimate the pKₐ values based on the protons’ environments in each structure using the reference table provided.
![The image contains a chemical structure diagram on the left, and a table listing chemical species and their pKa values on the right.
**Chemical Structure:**
- The diagram depicts a complex organic molecule. It includes several functional groups and atoms labeled as "H^c," "H^d," and others. The structure has a benzene ring fused with a five-membered nitrogen-containing ring, likely indicating a heterocyclic compound.
**Table of Chemical Species and pKa Values:**
1. **O=C(CH₃)₂** - pKa: 19
2. **H₂O** - pKa: 16
3. **O=C(NH₂)(CH₃)** - pKa: 15
4. **NH₄⁺** - pKa: 9
5. **O=CH₃COH** - pKa: 5
6. **H₃O⁺** - pKa: −2
The pKa values represent the strength of an acid, with lower pKa values indicating a stronger acid. The given values help in understanding the acidity of various chemical species.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F70c6702f-1254-4f2b-ba5a-ac93276291c3%2Ff3b0c4f8-2a93-40f5-82cb-020b66e451ef%2F5orcyi_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The image contains a chemical structure diagram on the left, and a table listing chemical species and their pKa values on the right.
**Chemical Structure:**
- The diagram depicts a complex organic molecule. It includes several functional groups and atoms labeled as "H^c," "H^d," and others. The structure has a benzene ring fused with a five-membered nitrogen-containing ring, likely indicating a heterocyclic compound.
**Table of Chemical Species and pKa Values:**
1. **O=C(CH₃)₂** - pKa: 19
2. **H₂O** - pKa: 16
3. **O=C(NH₂)(CH₃)** - pKa: 15
4. **NH₄⁺** - pKa: 9
5. **O=CH₃COH** - pKa: 5
6. **H₃O⁺** - pKa: −2
The pKa values represent the strength of an acid, with lower pKa values indicating a stronger acid. The given values help in understanding the acidity of various chemical species.
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY