Using just a periodic table (not a table of electronegativities), decide which of these is likely to be the most polar bond. 3A 4A 5A 6A 7A 6 7 CN 13 14 15 16 17 Al Si P S CI 5 B 8 9 O F 31 32 33 34 35 Ga Ge As Se Br 49 50 51 52 53 In Sn Sb Te I 81 82 83 84 85 TI Pb Bi Po At P-CI S-CI As-Cl Sb-Cl

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### Analyzing Polar Bonds Using a Periodic Table

**Objective:**  
Using a periodic table (not a table of electronegativities), decide which of these bonds is likely to be the most polar.

**Elements to Consider:**
- Phosphorus (P) - Chlorine (Cl)
- Sulfur (S) - Chlorine (Cl)
- Arsenic (As) - Chlorine (Cl)
- Antimony (Sb) - Chlorine (Cl)

**Periodic Table Analysis:**

The provided periodic table highlights groups 3A to 7A, showcasing elements from different periods. Each group's elements are boxed and color-coded as follows:

- **3A**: Boron (B), Aluminum (Al), Gallium (Ga), Indium (In), Thallium (Tl)
- **4A**: Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), Lead (Pb)
- **5A**: Nitrogen (N), Phosphorus (P), Arsenic (As), Antimony (Sb), Bismuth (Bi)
- **6A**: Oxygen (O), Sulfur (S), Selenium (Se), Tellurium (Te), Polonium (Po)
- **7A**: Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I), Astatine (At)

**Determining Polarity:**

- **Polarity is often inferred from the position of elements in the periodic table:**
  - Elements further apart in the periodic table, especially across groups, generally have greater differences in electronegativity, leading to more polar bonds.
  - Chlorine, located in group 7A, is one of the most electronegative elements.

- **Predictions:**
  - Comparing the given options, sulfur (S) and chlorine (Cl) are chosen:
    - **Sulfur-Chlorine (S–Cl)** is selected as the most polar bond.
    - This selection is due to sulfur being directly adjacent to chlorine in the 6A group, suggesting a significant but manageable difference in their tendencies to attract electrons.

Understanding the periodic trends can aid in predicting bond polarity, with elements situated further right and higher up generally exhibiting greater electronegativity.
Transcribed Image Text:### Analyzing Polar Bonds Using a Periodic Table **Objective:** Using a periodic table (not a table of electronegativities), decide which of these bonds is likely to be the most polar. **Elements to Consider:** - Phosphorus (P) - Chlorine (Cl) - Sulfur (S) - Chlorine (Cl) - Arsenic (As) - Chlorine (Cl) - Antimony (Sb) - Chlorine (Cl) **Periodic Table Analysis:** The provided periodic table highlights groups 3A to 7A, showcasing elements from different periods. Each group's elements are boxed and color-coded as follows: - **3A**: Boron (B), Aluminum (Al), Gallium (Ga), Indium (In), Thallium (Tl) - **4A**: Carbon (C), Silicon (Si), Germanium (Ge), Tin (Sn), Lead (Pb) - **5A**: Nitrogen (N), Phosphorus (P), Arsenic (As), Antimony (Sb), Bismuth (Bi) - **6A**: Oxygen (O), Sulfur (S), Selenium (Se), Tellurium (Te), Polonium (Po) - **7A**: Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I), Astatine (At) **Determining Polarity:** - **Polarity is often inferred from the position of elements in the periodic table:** - Elements further apart in the periodic table, especially across groups, generally have greater differences in electronegativity, leading to more polar bonds. - Chlorine, located in group 7A, is one of the most electronegative elements. - **Predictions:** - Comparing the given options, sulfur (S) and chlorine (Cl) are chosen: - **Sulfur-Chlorine (S–Cl)** is selected as the most polar bond. - This selection is due to sulfur being directly adjacent to chlorine in the 6A group, suggesting a significant but manageable difference in their tendencies to attract electrons. Understanding the periodic trends can aid in predicting bond polarity, with elements situated further right and higher up generally exhibiting greater electronegativity.
Expert Solution
Step 1

More the electronegativity difference between two atoms more will be the polar bond between them. 

We know that from top to bottom in periodic table electronegativity decrease whereas moves from left to right in a periodic table electronegativity increase.

Hence, electronegativity order 

Cl > S > P > As > Sb 

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