Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B с observations This reaction is spontaneous only below 85. °C. This reaction is spontaneous except below. -1. °C but proceeds at a slower rate below 93. °C. The reverse of this reaction is always spontaneous but proceeds slower at temperatures below - 1. °C. AH is AS is conclusions AH is AS is AH is ΔS is X ✓(pick one) positive negative unknown (pick one) (pick one) (pick one) (pick one) S
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B с observations This reaction is spontaneous only below 85. °C. This reaction is spontaneous except below. -1. °C but proceeds at a slower rate below 93. °C. The reverse of this reaction is always spontaneous but proceeds slower at temperatures below - 1. °C. AH is AS is conclusions AH is AS is AH is ΔS is X ✓(pick one) positive negative unknown (pick one) (pick one) (pick one) (pick one) S
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Determining Reaction Enthalpy and Entropy Signs**
To analyze the chemical reactions based on the observations provided, use the table below to determine whether the reaction enthalpy (\(\Delta H\)) and reaction entropy (\(\Delta S\)) are positive, negative, or unknown.
_Note: If insufficient information is provided to determine a sign, select "unknown."_
---
**Reactions and Observations:**
1. **Reaction A**
- **Observation:** This reaction is spontaneous only below 85°C.
- **Conclusions:**
- \(\Delta H\) is (pick one: positive, negative, unknown)
- \(\Delta S\) is (pick one: positive, negative, unknown)
2. **Reaction B**
- **Observation:** This reaction is spontaneous except below -1°C, but proceeds at a slower rate below 93°C.
- **Conclusions:**
- \(\Delta H\) is (pick one: positive, negative, unknown)
- \(\Delta S\) is (pick one: positive, negative, unknown)
3. **Reaction C**
- **Observation:** The reverse of this reaction is always spontaneous but proceeds slower at temperatures below -1°C.
- **Conclusions:**
- \(\Delta H\) is (pick one: positive, negative, unknown)
- \(\Delta S\) is (pick one: positive, negative, unknown)
Use these observations along with your knowledge of thermodynamics to deduce the signs of \(\Delta H\) and \(\Delta S\) for each reaction.
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