Use the following character table for tetrahedral point group (To) to answer the following questions: Ta E 8C3 30 6S4 60d Ai +1 +1 +1 +1 +1 x²+y²+z² Az +1 +1 +1 -1 -1 E +2 -1 +2 0 0 (2x²-x²-y², x²-y²) T₁ +3 0 -1 +1 -1 (Rx, Ry, Rz) T₂ +3 0 -1 -1 +1 (x, y, z) (xy, xz, yz) (a) determine the orbitals symmetries of the central metal atom for tetrahedral metal complexes (ML4). (b) draw symmetry labelled molecular orbital (MO) diagram for ML4. Given that the ligand group orbitals (LGOs) symmetries are ai and tz. (c) clearly depict bonding, σ(a) and antibonding, o*(a1) MOs. + (d) use the above (part a) MO diagram to show the electron filling for tetrahedral [Ni(CO)4].

Use the following character table for tetrahedral point group (To) to answer the following questions: Ta E 8C3 30 6S4 60d Ai +1 +1 +1 +1 +1 x²+y²+z² Az +1 +1 +1 -1 -1 E +2 -1 +2 0 0 (2x²-x²-y², x²-y²) T₁ +3 0 -1 +1 -1 (Rx, Ry, Rz) T₂ +3 0 -1 -1 +1 (x, y, z) (xy, xz, yz) (a) determine the orbitals symmetries of the central metal atom for tetrahedral metal complexes (ML4). (b) draw symmetry labelled molecular orbital (MO) diagram for ML4. Given that the ligand group orbitals (LGOs) symmetries are ai and tz. (c) clearly depict bonding, σ(a) and antibonding, o*(a1) MOs. + (d) use the above (part a) MO diagram to show the electron filling for tetrahedral [Ni(CO)4].

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Use the following character table for tetrahedral point group (To) to answer the following questions: Ta E 8C3 30 6S4 60d Ai +1 +1 +1 +1 +1 x²+y²+z² Az +1 +1 +1 -1 -1 E +2 -1 +2 0 0 (2x²-x²-y², x²-y²) T₁ +3 0 -1 +1 -1 (Rx, Ry, Rz) T₂ +3 0 -1 -1 +1 (x, y, z) (xy, xz, yz) (a) determine the orbitals symmetries of the central metal atom for tetrahedral metal complexes (ML4). (b) draw symmetry labelled molecular orbital (MO) diagram for ML4. Given that the ligand group orbitals (LGOs) symmetries are ai and tz. (c) clearly depict bonding, σ(a) and antibonding, o*(a1) MOs. + (d) use the above (part a) MO diagram to show the electron filling for tetrahedral [Ni(CO)4].
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