uestion 3 [20] 3.1 Propose structures for compounds that fit the following data: a) A ketone with M+ = 72 and fragments at m/z = 57 and m/z = 29 (3) b) An alkane with M+ = 86 and fragments at m/z = 71, m/z = 41 and m/z = 15 (4) 3.2 Propose fragmentation patterns of the molecules below to determine which molecule will show m/z peaks at 43, 57, 87, 101 and 116: a) Isopropyl bromide b) Propyl chloride c) sec-Butyl isopropyl ether (13)
uestion 3 [20] 3.1 Propose structures for compounds that fit the following data: a) A ketone with M+ = 72 and fragments at m/z = 57 and m/z = 29 (3) b) An alkane with M+ = 86 and fragments at m/z = 71, m/z = 41 and m/z = 15 (4) 3.2 Propose fragmentation patterns of the molecules below to determine which molecule will show m/z peaks at 43, 57, 87, 101 and 116: a) Isopropyl bromide b) Propyl chloride c) sec-Butyl isopropyl ether (13)
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.28P: Following is the mass spectrum of 3-methyl-2-butanol. The molecular ion m/z 88 does not appear in...
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Question 3 [20]
3.1 Propose structures for compounds that fit the following data:
a) A
(3)
b) An
(4)
3.2 Propose fragmentation patterns of the molecules below to determine which molecule will
show m/z peaks at 43, 57, 87, 101 and 116:
a) Isopropyl bromide
b) Propyl chloride
c) sec-Butyl isopropyl ether
(13)
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