2-Methyl-3-pentanol reacts with PCC to form compound F. () Draw the structure of F. (ii) In the mass spectrum, identify the m/z value of the molecular ion peak for compound F. (iii) Fragmentation of radical cation F exhibits two fragment ion peaks at m/z 57 and m/z 71. Propose the structures of these two fragments.
2-Methyl-3-pentanol reacts with PCC to form compound F. () Draw the structure of F. (ii) In the mass spectrum, identify the m/z value of the molecular ion peak for compound F. (iii) Fragmentation of radical cation F exhibits two fragment ion peaks at m/z 57 and m/z 71. Propose the structures of these two fragments.
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL2: Mass Spectrometry
Section: Chapter Questions
Problem 3E
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![1 (c) 2-Methyl-3-pentanol reacts with PCC to form compound F.
(i) Draw the structure of F.
(ii) In the mass spectrum, identify the m/z value of the molecular ion peak for compound F.
(ii) Fragmentation of radical cation F exhibits two fragment ion peaks at m/z 57 and m/z 71. Propose
the structures of these two fragments.
(iv) Draw the resonance structure for each of the cation in (iii).](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F05a204b4-2b97-4928-8418-8ef90cc20188%2F7ea80a31-7087-413d-9a3b-2b273adb81f8%2F47hrmug_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1 (c) 2-Methyl-3-pentanol reacts with PCC to form compound F.
(i) Draw the structure of F.
(ii) In the mass spectrum, identify the m/z value of the molecular ion peak for compound F.
(ii) Fragmentation of radical cation F exhibits two fragment ion peaks at m/z 57 and m/z 71. Propose
the structures of these two fragments.
(iv) Draw the resonance structure for each of the cation in (iii).
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