Homework Help is Here – Start Your Trial Now!
Science
Chemistry
The intensity of M+, M+1, and M+2 peak are 100.0, 6.8, 31.9. The compound contains carbons, hydrogens, and a heteroatom. What is the molecular formula of the compound? (use format CXHYZ, where Z is heteroatom) 100 MS-NW-549s 80 60 40 20 10 20 30 40 50 60 70 80 90 100 110 Relative Intensity

The intensity of M+, M+1, and M+2 peak are 100.0, 6.8, 31.9. The compound contains carbons, hydrogens, and a heteroatom. What is the molecular formula of the compound? (use format CXHYZ, where Z is heteroatom) 100 MS-NW-549s 80 60 40 20 10 20 30 40 50 60 70 80 90 100 110 Relative Intensity

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question
### Mass Spectrometry Analysis: Determining Molecular Formula In this educational exercise, we are analyzing the mass spectrometry data of an unknown compound to determine its molecular formula. The compound in question contains carbon (C), hydrogen (H), and a heteroatom (Z). #### Given Data - The intensity of M+, M+1, and M+2 peaks are 100.0, 6.8, and 31.9, respectively. #### Objective - Determine the molecular formula of the compound (in the format CxHyZ). #### Understanding the Graph The mass spectrum displayed provides the relative intensity of detected ions plotted against their mass-to-charge ratio (m/z). 1. **X-Axis (m/z ratio)**: - Values range from 10 to 120. - This axis represents the mass-to-charge ratio of the ions detected. 2. **Y-Axis (Relative Intensity)**: - Values range from 0 to 100. - This axis represents the intensity of the ion peaks relative to the most intense peak. 3. **Key Peaks**: - The most intense peak (M+) is normalized to 100. - The subsequent peaks at M+1 and M+2 highlight the presence of isotopes and heteroatoms in the compound. ##### Peak Distribution Analysis - **M+ Peak (Base Peak)**: This is typically the molecular ion peak; here it has an intensity of 100. - **M+1 Peak (Isotope Peak)**: The next peak has a relative intensity of 6.8. - **M+2 Peak**: This peak, with a significant intensity of 31.9, suggests the presence of a heteroatom that has isotopes contributing significantly to this peak (e.g., sulfur, chlorine, or bromine). #### Steps to Determine the Molecular Formula 1. **Identify the Base Peak (M+) for Molecular Mass**: - The base peak represents the molecular ion (M), and helps in determining the molecular mass of the compound. 2. **Evaluate the Contributions of C, H, and Heteroatom (Z)**: - The M+1 peak often arises due to 13C isotopes. - The M+2 peak can indicate the presence of heteroatoms like Cl or Br, which have significant isotopic patterns. 3. **Apply Intensity Ratios**: - Use the
Transcribed Image Text:### Mass Spectrometry Analysis: Determining Molecular Formula In this educational exercise, we are analyzing the mass spectrometry data of an unknown compound to determine its molecular formula. The compound in question contains carbon (C), hydrogen (H), and a heteroatom (Z). #### Given Data - The intensity of M+, M+1, and M+2 peaks are 100.0, 6.8, and 31.9, respectively. #### Objective - Determine the molecular formula of the compound (in the format CxHyZ). #### Understanding the Graph The mass spectrum displayed provides the relative intensity of detected ions plotted against their mass-to-charge ratio (m/z). 1. **X-Axis (m/z ratio)**: - Values range from 10 to 120. - This axis represents the mass-to-charge ratio of the ions detected. 2. **Y-Axis (Relative Intensity)**: - Values range from 0 to 100. - This axis represents the intensity of the ion peaks relative to the most intense peak. 3. **Key Peaks**: - The most intense peak (M+) is normalized to 100. - The subsequent peaks at M+1 and M+2 highlight the presence of isotopes and heteroatoms in the compound. ##### Peak Distribution Analysis - **M+ Peak (Base Peak)**: This is typically the molecular ion peak; here it has an intensity of 100. - **M+1 Peak (Isotope Peak)**: The next peak has a relative intensity of 6.8. - **M+2 Peak**: This peak, with a significant intensity of 31.9, suggests the presence of a heteroatom that has isotopes contributing significantly to this peak (e.g., sulfur, chlorine, or bromine). #### Steps to Determine the Molecular Formula 1. **Identify the Base Peak (M+) for Molecular Mass**: - The base peak represents the molecular ion (M), and helps in determining the molecular mass of the compound. 2. **Evaluate the Contributions of C, H, and Heteroatom (Z)**: - The M+1 peak often arises due to 13C isotopes. - The M+2 peak can indicate the presence of heteroatoms like Cl or Br, which have significant isotopic patterns. 3. **Apply Intensity Ratios**: - Use the
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 5 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
NMR Spectroscopy of Organic Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS