a) b) Predicting Acidity Rank the following compounds in order of increasing acidity: 1 1 1 OH LOH Rel. Intensity 100 80 60 40 20 2 0.0+ OH 0.0 OH H₂ 0: Alcohols and Ethers Interpreting a Mass Spectrum give a peak at m/z = 45? 20 3 3 Example: Propose a structure for the following alcohol using the mass spectrum below (NOTE: there is a very small peak at m/z = 88) unknown MASS SPECTRUM 40 OH OH Ö-H 3 4 60 Hints: This is an alcohol, it has a mass of 88 so first determine the formula, then draw the possible structures. Now, which structure will fragment to OH OH 80 100

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Chapter1: Chemical Foundations
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a)
b)
Acidity of Alcohols, Phenols and Thiols
Predicting Acidity
Rank the following compounds in order of increasing acidity:
1
1
OH
OH
Rel. Intensity
100
80
60
40
20
OH
0.0
2
0.0
2
OH
Alcohols and Ethers
Interpreting a Mass Spectrum give a peak at m/z = 45?
20
O
3
40
3
Example: Propose a structure for the following alcohol using the mass
spectrum below (NOTE: there is a very small peak at m/z = 88)
unknown
MASS SPECTRUM
OH
LOH
m/z
4
3
60
Hints: This is an alcohol, it has a mass of 88 so first
determine the formula, then draw the possible
structures. Now, which structure will fragment to
OH
OH
80
4
100
Transcribed Image Text:a) b) Acidity of Alcohols, Phenols and Thiols Predicting Acidity Rank the following compounds in order of increasing acidity: 1 1 OH OH Rel. Intensity 100 80 60 40 20 OH 0.0 2 0.0 2 OH Alcohols and Ethers Interpreting a Mass Spectrum give a peak at m/z = 45? 20 O 3 40 3 Example: Propose a structure for the following alcohol using the mass spectrum below (NOTE: there is a very small peak at m/z = 88) unknown MASS SPECTRUM OH LOH m/z 4 3 60 Hints: This is an alcohol, it has a mass of 88 so first determine the formula, then draw the possible structures. Now, which structure will fragment to OH OH 80 4 100
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