a) b) Predicting Acidity Rank the following compounds in order of increasing acidity: 1 1 1 OH LOH Rel. Intensity 100 80 60 40 20 2 0.0+ OH 0.0 OH H₂ 0: Alcohols and Ethers Interpreting a Mass Spectrum give a peak at m/z = 45? 20 3 3 Example: Propose a structure for the following alcohol using the mass spectrum below (NOTE: there is a very small peak at m/z = 88) unknown MASS SPECTRUM 40 OH OH Ö-H 3 4 60 Hints: This is an alcohol, it has a mass of 88 so first determine the formula, then draw the possible structures. Now, which structure will fragment to OH OH 80 100
a) b) Predicting Acidity Rank the following compounds in order of increasing acidity: 1 1 1 OH LOH Rel. Intensity 100 80 60 40 20 2 0.0+ OH 0.0 OH H₂ 0: Alcohols and Ethers Interpreting a Mass Spectrum give a peak at m/z = 45? 20 3 3 Example: Propose a structure for the following alcohol using the mass spectrum below (NOTE: there is a very small peak at m/z = 88) unknown MASS SPECTRUM 40 OH OH Ö-H 3 4 60 Hints: This is an alcohol, it has a mass of 88 so first determine the formula, then draw the possible structures. Now, which structure will fragment to OH OH 80 100
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:a)
b)
Acidity of Alcohols, Phenols and Thiols
Predicting Acidity
Rank the following compounds in order of increasing acidity:
1
1
OH
OH
Rel. Intensity
100
80
60
40
20
OH
0.0
2
0.0
2
OH
Alcohols and Ethers
Interpreting a Mass Spectrum give a peak at m/z = 45?
20
O
3
40
3
Example: Propose a structure for the following alcohol using the mass
spectrum below (NOTE: there is a very small peak at m/z = 88)
unknown
MASS SPECTRUM
OH
LOH
m/z
4
3
60
Hints: This is an alcohol, it has a mass of 88 so first
determine the formula, then draw the possible
structures. Now, which structure will fragment to
OH
OH
80
4
100
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