The following MS spectrum is for a compound which contains one oxygen atom (as well as C and H, of course, but no other atoms). Propose a structure which is consistent with this MS; also identify the species responsible for each peak whose numerical m/z is given (remember resonance!). % ADURC А b u n 2 C e d a 100 80 60 40 20 0 20 31 40 60 m/z 77 80 91 % (M+1)/M = 7.93 100 107 108 120

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....
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The following MS spectrum is for a compound which contains one oxygen atom (as well as C
and H, of course, but no other atoms). Propose a structure which is consistent with this MS;
also identify the species responsible for each peak whose numerical m/z is given (remember
resonance!).
OP ALTAOSACO
b
d
100
80
60
40
20
0
0
20
31
40
60
m/z
77
80
91
% (M+1)/M = 7.93
100
107
108
120
Transcribed Image Text:The following MS spectrum is for a compound which contains one oxygen atom (as well as C and H, of course, but no other atoms). Propose a structure which is consistent with this MS; also identify the species responsible for each peak whose numerical m/z is given (remember resonance!). OP ALTAOSACO b d 100 80 60 40 20 0 0 20 31 40 60 m/z 77 80 91 % (M+1)/M = 7.93 100 107 108 120
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