Treatment of (S)-(+)-5-methyl-2-cyclohexenone with lithium dimethylcuprate gives, after protonolysis, a good yield of a mixture containing mostly dextrorotatory ketone A and a trace of optically inactive isomer B. Treatment of A with zinc amalgam and HCl affords optically active, dextrorotatory hydrocarbon C. Identify compounds A. B, and C, including stereochemical configurations. Be sure to explicitly draw H and both wedge and dash bonds at any configuration center. Draw compound A. Draw compound B.

Treatment of (S)-(+)-5-methyl-2-cyclohexenone with lithium dimethylcuprate gives, after protonolysis, a good yield of a mixture containing mostly dextrorotatory ketone A and a trace of optically inactive isomer B. Treatment of A with zinc amalgam and HCl affords optically active, dextrorotatory hydrocarbon C. Identify compounds A. B, and C, including stereochemical configurations. Be sure to explicitly draw H and both wedge and dash bonds at any configuration center. Draw compound A. Draw compound B.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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