Time restraint) What differences in the IR spectra of the reactant and product in each of the following transformations would enable you to tell that each reaction took place? Be specific and give numbers please. Include presence/absences/shifts of all distinguishing peaks. Please use the the IR correlation table attacthed to this question. Thank you again

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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(Time restraint) What differences in the IR spectra of the reactant and product in each of the following transformations would enable you to tell that each reaction took place? Be specific and give numbers please. Include presence/absences/shifts of all distinguishing peaks. Please use the the IR correlation table attacthed to this question. Thank you again.

Functional Group
Frequency (cm!)
Intensity and Comments
Alkanes
С-Н
2980-2850
medium to strong
C-C
1480-1420
medium
Alkenes
medium; very weak for trans
strong
strong
weak to medium
=C-H stretch
3150-3000
980-960 (trans)
730-665 (cis)
—С-Н bend
C=C
1680-1600
Alkynes
=C-H
3350-3300
strong
weak to medium
C=C
2260-2100
Alkyl halides
C-Cl
800-600
strong
strong
C-Br
600-500
C-I
500
strong
Alcohols
strong and broad
strong
O-H
3650-3300
C-O
1350-1050
Amines
N-H
3500-3100
medium and strong; 1° amines-2 bands; 2° amines-1 band
medium
С-N
~1200
Aromatics
C-H stretch
3080-3020
weak to medium
С-H bend
900-730
strong
weak to medium
C=C
1650-1580
Carbonyls (C=O)
Ketones
1730-1700
strong
strong; also has a O=C-H doublet at ~2700 & 2800 cm'
strong; also has C–O stretch
strong; 1° and 2° amides also have N-H stretch
strong; also has O–H stretch
strong; doublet
strong
medium
Aldehydes
1730-1700
Esters
1750-1735
Amides
1680-1630
Acids
1730-1700
Acid Anhydride
1850-1740
Acid Chlorides
1820-1770
Nitrile (C=N)
Nitro (NO2)
2200-2250
Doublet at:
strong
1570-1550 &
1380-1360
Transcribed Image Text:Functional Group Frequency (cm!) Intensity and Comments Alkanes С-Н 2980-2850 medium to strong C-C 1480-1420 medium Alkenes medium; very weak for trans strong strong weak to medium =C-H stretch 3150-3000 980-960 (trans) 730-665 (cis) —С-Н bend C=C 1680-1600 Alkynes =C-H 3350-3300 strong weak to medium C=C 2260-2100 Alkyl halides C-Cl 800-600 strong strong C-Br 600-500 C-I 500 strong Alcohols strong and broad strong O-H 3650-3300 C-O 1350-1050 Amines N-H 3500-3100 medium and strong; 1° amines-2 bands; 2° amines-1 band medium С-N ~1200 Aromatics C-H stretch 3080-3020 weak to medium С-H bend 900-730 strong weak to medium C=C 1650-1580 Carbonyls (C=O) Ketones 1730-1700 strong strong; also has a O=C-H doublet at ~2700 & 2800 cm' strong; also has C–O stretch strong; 1° and 2° amides also have N-H stretch strong; also has O–H stretch strong; doublet strong medium Aldehydes 1730-1700 Esters 1750-1735 Amides 1680-1630 Acids 1730-1700 Acid Anhydride 1850-1740 Acid Chlorides 1820-1770 Nitrile (C=N) Nitro (NO2) 2200-2250 Doublet at: strong 1570-1550 & 1380-1360
НО.
Transcribed Image Text:НО.
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