Why are solid forms of the sample are not suitable for Uv-visible spectroscopy and Fluorescence spectroscopy?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter15: Molecular Luminescence Spectrometry
Section: Chapter Questions
Problem 15.6QAP
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Why are solid forms of the sample are not suitable for Uv-visible spectroscopy and Fluorescence spectroscopy? Please shortly answer at your own words. Answer should be specific (3-4 lines). 

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