This is the spectral data for 4-cyclohexene-cis-1,2-dicarboxylic acid - Can you tell whether you have the cis or trans 4-cyclohexene-1,2-dicarboxylic acid based on the number of signals seen on 13C NMR? anhydride (CDCI3).(b) 13C NMR data: 8 47.6, 53.5, 136.1, 171.9.1008060 -40CO2H20 -"CO2HFigure 12.11IR spectrum of 4-cyclohexene-cis-1,2-dicarboxylic acid (IR card).T40003600320028002400200018001600140012001000800600Wavenumber (cm-1)CO2H|に"CO2HCD3SOCD,HIIT12.4 ppm2.94 ppm2.40ppm22109.8764321Figure 12.12NMR data for 4-cyclohexene-cis-1,2-dicarboxylic acid(DMSO-d,).8, ppmпе-(a) 'H NMR spectrum (300 MHz).(b) 13C NMR data: 8 25.9, 39.2, 125.2, 174.9.Transmittance (%)

Given 13C-NMR peak are δ 25.9, 39.2, 125.2, 174.9 There are total 4 peak given.

Answered: This is the spectral data for…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

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This is the spectral data for 4-cyclohexene-cis-1,2-dicarboxylic acid - Can you tell whether you have the cis or trans 4-cyclohexene-1,2-dicarboxylic acid based on the number of signals seen on ¹³C NMR?

anhydride (CDCI3).
(b) 13C NMR data: 8 47.6, 53.5, 136.1, 171.9.
100
80
60 -
40
CO2H
20 -
"CO2H
Figure 12.11
IR spectrum of 4-cyclohexene-
cis-1,2-dicarboxylic acid (IR card).
T
4000
3600
3200
2800
2400
2000
1800
1600
1400
1200
1000
800
600
Wavenumber (cm-1)
CO2H
|に
"CO2H
CD3SOCD,H
IIT
12.4 ppm
2.94 ppm
2.40
ppm
22
10
9.
8
7
6
4
3
2
1
Figure 12.12
NMR data for 4-cyclohexene-
cis-1,2-dicarboxylic acid
(DMSO-d,).
8, ppm
пе-
(a) 'H NMR spectrum (300 MHz).
(b) 13C NMR data: 8 25.9, 39.2, 125.2, 174.9.
Transmittance (%)

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