How many signals are expected in the decoupled ¹³C NMR spectrum of 3-bromotoluene?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Question:**

How many signals are expected in the decoupled \(^{13}C\) NMR spectrum of 3-bromotoluene?

**Diagram Explanation:**

The diagram shows the molecular structure of 3-bromotoluene. It is a benzene ring substituted with a bromine (Br) atom and a methyl (CH\(_3\)) group.

- **Benzene Ring**: The benzene ring in the structure exhibits a regular hexagon of alternating double bonds.
- **Substituents**: 
  - The bromine atom is attached to the third carbon of the ring.
  - The methyl group (CH\(_3\)) is attached to the carbon at the opposite position in the benzene ring of the bromine atom.

In \(^{13}C\) NMR spectroscopy, each unique carbon environment gives rise to a separate signal. The molecule 3-bromotoluene has unique carbon environments due to the bromine and methyl substituents affecting the symmetry of the benzene ring. Therefore, the number of expected \(^{13}C\) NMR signals equals the number of distinct carbon environments in this structure.
Transcribed Image Text:**Question:** How many signals are expected in the decoupled \(^{13}C\) NMR spectrum of 3-bromotoluene? **Diagram Explanation:** The diagram shows the molecular structure of 3-bromotoluene. It is a benzene ring substituted with a bromine (Br) atom and a methyl (CH\(_3\)) group. - **Benzene Ring**: The benzene ring in the structure exhibits a regular hexagon of alternating double bonds. - **Substituents**: - The bromine atom is attached to the third carbon of the ring. - The methyl group (CH\(_3\)) is attached to the carbon at the opposite position in the benzene ring of the bromine atom. In \(^{13}C\) NMR spectroscopy, each unique carbon environment gives rise to a separate signal. The molecule 3-bromotoluene has unique carbon environments due to the bromine and methyl substituents affecting the symmetry of the benzene ring. Therefore, the number of expected \(^{13}C\) NMR signals equals the number of distinct carbon environments in this structure.
Expert Solution
steps

Step by step

Solved in 3 steps with 1 images

Blurred answer
Knowledge Booster
NMR Spectroscopy of Organic Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY