Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Title: Identifying Molecules with a Singlet ¹H NMR Splitting Pattern**
**Instructions:**
Select all molecules with a "singlet" ¹H NMR splitting pattern for the indicated hydrogen.
**Molecules:**
- **A:** Two hydrogens on a strained four-membered ring, adjacent to a carbonyl group.
- **B:** A cyclic ester (lactone) with one hydrogen indicated, adjacent to an oxygen atom.
- **C:** A cyclic structure with a methyl group; one hydrogen is highlighted.
- **D:** Another cyclic structure with an isolated hydrogen, adjacent to a carbonyl group.
**Options:**
- [ ] B
- [ ] A
- [ ] D
- [ ] C
**Note:**
A handwritten note reads: "More than one can be picked."
**Explanation:**
This exercise involves analyzing the chemical environment of hydrogens in different molecular structures to determine which hydrogens will present a singlet pattern in a ¹H NMR spectrum. A singlet occurs when the hydrogen is not coupled to any neighboring hydrogens.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb5f1630e-c465-44f2-a868-b429d99d07e1%2Fa9dd8682-7053-468c-b1c4-1c834d06eca8%2Fk3jls1n_processed.png&w=3840&q=75)
Transcribed Image Text:**Title: Identifying Molecules with a Singlet ¹H NMR Splitting Pattern**
**Instructions:**
Select all molecules with a "singlet" ¹H NMR splitting pattern for the indicated hydrogen.
**Molecules:**
- **A:** Two hydrogens on a strained four-membered ring, adjacent to a carbonyl group.
- **B:** A cyclic ester (lactone) with one hydrogen indicated, adjacent to an oxygen atom.
- **C:** A cyclic structure with a methyl group; one hydrogen is highlighted.
- **D:** Another cyclic structure with an isolated hydrogen, adjacent to a carbonyl group.
**Options:**
- [ ] B
- [ ] A
- [ ] D
- [ ] C
**Note:**
A handwritten note reads: "More than one can be picked."
**Explanation:**
This exercise involves analyzing the chemical environment of hydrogens in different molecular structures to determine which hydrogens will present a singlet pattern in a ¹H NMR spectrum. A singlet occurs when the hydrogen is not coupled to any neighboring hydrogens.
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