The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does:   (p+a n2/V2)(V-nb) = nRT   The van der Waals equation of state. R stands for the gas constant and n  for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below.   What are the units of a?   What are the units of b?   For argon the numerical value of a is 1.337 and the numerical value of b is 0.0320. Use the van der Waals equation to calculate the pressure of a sample of argon at −100.0°C with a molar volume of 3.94/Lmol. Round your answer to 3 significant digits. = atm Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does:

 
(p+a n2/V2)(V-nb) = nRT
  The van der Waals equation of state. R stands for the gas constant and n
 for moles of gas.

The parameters a and b must be determined for each gas from experimental data.

Use the van der Waals equation to answer the questions in the table below.

 

What are the units of a?

 

What are the units of b?

 

For argon the numerical value of a is 1.337 and the numerical value of b is 0.0320.

Use the van der Waals equation to calculate the pressure of a sample of argon at −100.0°C with a molar volume of 3.94/Lmol. Round your answer to 3 significant digits.

= atm

Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also.

= atm
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Knowledge Booster
Absorption and Adsorption
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY