p+a- |(v-nb)=nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. 2 atm·L What are the units of a? mol What are the units of b? mol For carbon dioxide the numerical value of a is 3.592 and the numerical value of b is 0.0429. |atm Use the van der Waals equation to calculate the pressure of a sample of carbon dioxide at 70.0 °C with a molar volume of 4.50 L/mol. Round your answer to 3 significant digits. Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also. ||atm
p+a- |(v-nb)=nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. 2 atm·L What are the units of a? mol What are the units of b? mol For carbon dioxide the numerical value of a is 3.592 and the numerical value of b is 0.0429. |atm Use the van der Waals equation to calculate the pressure of a sample of carbon dioxide at 70.0 °C with a molar volume of 4.50 L/mol. Round your answer to 3 significant digits. Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also. ||atm
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### The van der Waals Equation of State
The van der Waals equation is given by:
\[
\left( p + a \frac{n^2}{V^2} \right) (V - nb) = nRT
\]
Where \( R \) is the gas constant and \( n \) is the number of moles of gas.
#### Parameters
- **\( a \)** and **\( b \)**: Specific to each gas, determined from experimental data.
### Units of Parameters
- **Units of \( a \):** \(\text{atm} \cdot \text{L}^2/\text{mol}^2\)
- **Units of \( b \):** \(\text{L/mol}\)
### Calculation Tasks
1. **Van der Waals Pressure Calculation:**
- For carbon dioxide, \( a = 3.592 \) and \( b = 0.0429 \).
- Calculate the pressure of a CO2 sample at 70.0 °C with a molar volume of 4.50 L/mol using the van der Waals equation.
- Provide your answer rounded to 3 significant digits.
- Final pressure: \(\boxed{\text{atm}}\)
2. **Ideal Gas Law Calculation:**
- Calculate the pressure of the same CO2 sample under the same conditions using the Ideal Gas Law.
- Round your answer to 3 significant digits.
- Final pressure: \(\boxed{\text{atm}}\)
### Diagram Description
There is no graph or diagram to describe in this material.
This content provides a foundational understanding of applying the van der Waals equation for calculating the pressure of gases, highlighting the importance of parameters \( a \) and \( b \), and compares results with the Ideal Gas Law for educational purposes.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4f2747d8-73cd-4f99-8eb9-7639fb8c9e08%2F6f5e775b-2b9e-4b98-935e-04d5024f1785%2Fsqiikr_processed.png&w=3840&q=75)
Transcribed Image Text:### The van der Waals Equation of State
The van der Waals equation is given by:
\[
\left( p + a \frac{n^2}{V^2} \right) (V - nb) = nRT
\]
Where \( R \) is the gas constant and \( n \) is the number of moles of gas.
#### Parameters
- **\( a \)** and **\( b \)**: Specific to each gas, determined from experimental data.
### Units of Parameters
- **Units of \( a \):** \(\text{atm} \cdot \text{L}^2/\text{mol}^2\)
- **Units of \( b \):** \(\text{L/mol}\)
### Calculation Tasks
1. **Van der Waals Pressure Calculation:**
- For carbon dioxide, \( a = 3.592 \) and \( b = 0.0429 \).
- Calculate the pressure of a CO2 sample at 70.0 °C with a molar volume of 4.50 L/mol using the van der Waals equation.
- Provide your answer rounded to 3 significant digits.
- Final pressure: \(\boxed{\text{atm}}\)
2. **Ideal Gas Law Calculation:**
- Calculate the pressure of the same CO2 sample under the same conditions using the Ideal Gas Law.
- Round your answer to 3 significant digits.
- Final pressure: \(\boxed{\text{atm}}\)
### Diagram Description
There is no graph or diagram to describe in this material.
This content provides a foundational understanding of applying the van der Waals equation for calculating the pressure of gases, highlighting the importance of parameters \( a \) and \( b \), and compares results with the Ideal Gas Law for educational purposes.
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