The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) 0 3 6 9 12 15 11.07 14.79 17.26 PTotal (kPa) 18.90 19.99 20.71 Pso₂Cl₂ Pso₂ Pctz Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as , and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Pso₂+ Pct₂ = (Po-5)+ 5 + 5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d).
The total pressure of the following system is used to monitor the progress of the chemical reaction. SO₂Cl₂(g) → SO₂(g) + Cl₂(g) The reaction is initiated, and the following data are obtained: Time (h) 0 3 6 9 12 15 11.07 14.79 17.26 PTotal (kPa) 18.90 19.99 20.71 Pso₂Cl₂ Pso₂ Pctz Additional information: As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as , and the initial pressure as Po, the total pressure is given by: Ptotal = Pso₂Cl₂ + Pso₂+ Pct₂ = (Po-5)+ 5 + 5 a) Calculate the pressure of each component at each time interval, i.e. complete the above table. b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂? (i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer. c) Determine the rate constant for this reaction. d) Give the rate equation describing the reaction. e) What is the half-life of this reaction? Show your calculation. f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate equation in (d).
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Assignment 3 (NCHE312)
The total pressure of the following system is used to monitor the progress of the chemical reaction.
SO₂Cl2(g) → SO₂(g) + Cl₂(g)
The reaction is initiated, and the following data are obtained:
0
3
6
9
12
15
Time (h)
PTotal (kPa)
14.79
17.26
18.90
11.07
19.99
20.71
Pso₂Cl₂
Pso₂
Pclz
Additional information:
As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one
mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the
initial pressure as Po, the total pressure is given by:
Ptotal = Pso₂Cl₂ + Ps0₂ + Pcl₂ = (Po-5 + 5 + 5
a) Calculate the pressure of each component at each time interval, i.e. complete the above table.
b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂?
(i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer.
c) Determine the rate constant for this reaction.
d) Give the rate equation describing the reaction.
e) What is the half-life of this reaction? Show your calculation.
f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate
equation in (d).
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folder. Deadline for submission: 08/06/2022 at 12pm
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Transcribed Image Text:09:00
Edit
סם
⠀
2
Assignment 3 (NCHE312)
The total pressure of the following system is used to monitor the progress of the chemical reaction.
SO₂Cl2(g) → SO₂(g) + Cl₂(g)
The reaction is initiated, and the following data are obtained:
0
3
6
9
12
15
Time (h)
PTotal (kPa)
14.79
17.26
18.90
11.07
19.99
20.71
Pso₂Cl₂
Pso₂
Pclz
Additional information:
As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one
mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the
initial pressure as Po, the total pressure is given by:
Ptotal = Pso₂Cl₂ + Ps0₂ + Pcl₂ = (Po-5 + 5 + 5
a) Calculate the pressure of each component at each time interval, i.e. complete the above table.
b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂?
(i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer.
c) Determine the rate constant for this reaction.
d) Give the rate equation describing the reaction.
e) What is the half-life of this reaction? Show your calculation.
f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate
equation in (d).
Convert your work into a single PDF file and upload it into your eFundi Dropbox
folder. Deadline for submission: 08/06/2022 at 12pm
DO
W
Mobile View
Share
PDF to DOC
Tools
Vol)
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HJ
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#(d)Give the rate equation describing the reaction.
#(e)What is the half life of this reaction?Show your calculations.
#(f) How long will the reaction take to come to an end? Show your calculations/derivation of the rate equation in (d).
Solution
Follow-up Question
![1 of 1
Assignment 3 (NCHE312)
The total pressure of the following system is used to monitor the progress of the chemical reaction.
SO₂Cl₂(g) → SO2(g) + Cl₂(g)
The reaction is initiated, and the following data are obtained:
Time (h)
PTotal (kPa)
Pso₂cl₂
Ps0₂
Pclz
0
11.07
3
6
14.79 17.26
9
18.90
12
19.99
15
20.71
Additional information:
As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one
mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the
initial pressure as Po, the total pressure is given by:
Ptotal = Pso₂Cl₂ + Pso₂+ Pcl₂ = (Po-5)+5+5
Convert your work into a single PDF file and upload it into your eFundi Dropbox
folder. Deadline for submission: 26/05/2023 at 12pm
a) Calculate the pressure of each component at each time interval, i.e. complete the above table.
b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂?
(i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer.
c) Determine the rate constant for this reaction.
d) Give the rate equation describing the reaction.
e) What is the half-life of this reaction? Show your calculation.
f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate
equation in (d).](https://content.bartleby.com/qna-images/question/6c66fd78-9a6d-45b2-89b8-80c35790033d/b72119d2-a3f3-46b6-a229-186a7286ff02/kiedzsk_thumbnail.png)
Transcribed Image Text:1 of 1
Assignment 3 (NCHE312)
The total pressure of the following system is used to monitor the progress of the chemical reaction.
SO₂Cl₂(g) → SO2(g) + Cl₂(g)
The reaction is initiated, and the following data are obtained:
Time (h)
PTotal (kPa)
Pso₂cl₂
Ps0₂
Pclz
0
11.07
3
6
14.79 17.26
9
18.90
12
19.99
15
20.71
Additional information:
As the reaction proceeds, stoichiometry dictates that for every mole of SO₂Cl₂ that dissociates one
mole of each of SO₂ and Cl₂ is produced. Defining the extent of dissociation/reaction as E, and the
initial pressure as Po, the total pressure is given by:
Ptotal = Pso₂Cl₂ + Pso₂+ Pcl₂ = (Po-5)+5+5
Convert your work into a single PDF file and upload it into your eFundi Dropbox
folder. Deadline for submission: 26/05/2023 at 12pm
a) Calculate the pressure of each component at each time interval, i.e. complete the above table.
b) Use a graphical method and determine what the order of the reaction is with respect to SO₂Cl₂?
(i) Show the plot as well as the linear fit of the data. (ii) Motivate your answer.
c) Determine the rate constant for this reaction.
d) Give the rate equation describing the reaction.
e) What is the half-life of this reaction? Show your calculation.
f) How long will the reaction take to come to an end? Show your calculation/derivation of the rate
equation in (d).
Solution
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