The selectivity coefficient, Kg+ µ+, for a K* ion-selective electrode is 0.00378. When the electrode is placed into a 1.80 x 10- M K* solution at pH 6.59, the potential is –0.159 V vs. SCE. If the pH of the solution is lowered to 1.25 and the ionic strength is kept constant, what is the potential of the electrode? Assume ß = 1 for the electrode.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter17: Electrochemistry And Its Applications
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The selectivity coefficient, Kg+ µ+ , for a K* ion-selective electrode is 0.00378. When the electrode is placed into a
1.80 x 10-5 M K+ solution at pH 6.59, the potential is –0.159 V vs. SCE. If the pH of the solution is lowered to 1.25 and the
ionic strength is kept constant, what is the potential of the electrode? Assume ß = 1 for the electrode.
E =
V vs. SCE
* TOOLS
x10
Transcribed Image Text:The selectivity coefficient, Kg+ µ+ , for a K* ion-selective electrode is 0.00378. When the electrode is placed into a 1.80 x 10-5 M K+ solution at pH 6.59, the potential is –0.159 V vs. SCE. If the pH of the solution is lowered to 1.25 and the ionic strength is kept constant, what is the potential of the electrode? Assume ß = 1 for the electrode. E = V vs. SCE * TOOLS x10
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