The Nernst equation is one of the most important equations in electrochemistry. To calculate the cell potential at non-standard - state conditions, the equation is EE-2.303RTn Flog10Q where E is the potential in volts, E is the standard potential in volts, R is the gas constant, T is the temperature in kelvins, n is the number of moles of electrons transferred, F is the Faraday constant, and Q is the reaction quotient. Using the common reference temperature, 25 °C or 298 K, the equation has the form E E-(0.0592n)logQ The reaction quotient has the usual form Q = [products]x[ reactants]y A table of standard reduction potentials gives the voltage at standard conditions, 1.00 M for all solutions and 1.00 atm for all gases. The Nernst equation allows for the calculation of the cell potential E at other conditions of concentration and pressure. Part A For the reaction 2Co3+ (aq) + 2CI-(aq)-> 2Co2 + (aq )+C12(g). E 0.483 V what is the cell potential at 25°

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The Nernst equation is one of the most important
equations in electrochemistry. To calculate the cell
potential at non-standard-state conditions, the
equation is E = E-2.303RTn Flog 10Q where E is the
potential in volts, Eo is the standard potential in volts, R
is the gas constant, T is the temperature in kelvins, n is
the number of moles of electrons transferred, F is the
Faraday constant, and Q is the reaction quotient. Using
the common reference temperature, 25 °C or 298 K, the
equation has the form E = E-(0.0592n)logQ The
reaction quotient has the usual form Q = [products]x[
reactants]y A table of standard reduction potentials
gives the voltage at standard conditions, 1.00 M for all
solutions and 1.00 atm for all gases. The Nernst
equation allows for the calculation of the cell potential E
at other conditions of concentration and pressure. Part
A For the reaction 2C03 + (aq) + 2CI-(aq)-> 2Co2 + (aq
)+ Cl2(g). E = 0.483 V what is the cell potential at 25°
C if the concentrations are [Co3+] = 9.20\times 10-2
M, [Co2+] 0.758 M, and [CI-] = 0.895 M, and the
pressure of C12 is PC12 = 3.10 atm ?
Transcribed Image Text:The Nernst equation is one of the most important equations in electrochemistry. To calculate the cell potential at non-standard-state conditions, the equation is E = E-2.303RTn Flog 10Q where E is the potential in volts, Eo is the standard potential in volts, R is the gas constant, T is the temperature in kelvins, n is the number of moles of electrons transferred, F is the Faraday constant, and Q is the reaction quotient. Using the common reference temperature, 25 °C or 298 K, the equation has the form E = E-(0.0592n)logQ The reaction quotient has the usual form Q = [products]x[ reactants]y A table of standard reduction potentials gives the voltage at standard conditions, 1.00 M for all solutions and 1.00 atm for all gases. The Nernst equation allows for the calculation of the cell potential E at other conditions of concentration and pressure. Part A For the reaction 2C03 + (aq) + 2CI-(aq)-> 2Co2 + (aq )+ Cl2(g). E = 0.483 V what is the cell potential at 25° C if the concentrations are [Co3+] = 9.20\times 10-2 M, [Co2+] 0.758 M, and [CI-] = 0.895 M, and the pressure of C12 is PC12 = 3.10 atm ?
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