The potential in an electrochemical cell, E, is related to the Gibb's free energy change (ΔG) for the overall cell redox reaction:(1) ΔG0 = -nFE0where n is the number of electrons transferred during the redox reaction, F is Faraday's constant (96,500 C / mol), and the superscript 0 indicates standard conditions (1 atm, 1 M concentrations, and 25 °C). Thus, a measurement of the cell voltage at standard conditions can be used to determine ΔG0.As an example, the following cell reaction:Zn(s)+Cu2+(aq) →Zn2+(aq)+Cu(m)generates a cell voltage of +1.10V under standard conditions. Based on the example from the previous section, calculate and enter below ΔG0 (with 3 sig figs) for this reaction in kJ/mol.

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The potential in an electrochemical cell, E, is related to the Gibb's free energy change (ΔG) for the overall cell redox reaction:

(1) ΔG0 = -nFE0

where n is the number of electrons transferred during the redox reaction, F is Faraday's constant (96,500 C / mol), and the superscript 0 indicates standard conditions (1 atm, 1 M concentrations, and 25 °C). Thus, a measurement of the cell voltage at standard conditions can be used to determine ΔG0.

As an example, the following cell reaction:

Zn(s)+Cu2+(aq) →Zn2+(aq)+Cu(m)

generates a cell voltage of +1.10V under standard conditions.

Based on the example from the previous section, calculate and enter below ΔG0 (with 3 sig figs) for this reaction in kJ/mol.

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