The reaction of cerium (IV) with thallium (I) is: 2Ce+4(aq) + Tl+1(aq) ⟶⟶ 2Ce+3(aq) + Tl+3(aq) The proposed mechanism for this reaction is: Ce+4(aq) + Mn+2(aq) ⟶⟶ Ce+3(aq) + Mn+3(aq) Ce+4(aq) + Mn+3(aq) ⟶⟶ Ce+3(aq) + Mn+4(aq) Mn+4(aq) + Tl+1(aq) ⟶⟶ Mn+2(aq) + Tl+3(aq) Identify the intermediate(s) and catalyst(s) if any.
The reaction of cerium (IV) with thallium (I) is: 2Ce+4(aq) + Tl+1(aq) ⟶⟶ 2Ce+3(aq) + Tl+3(aq) The proposed mechanism for this reaction is: Ce+4(aq) + Mn+2(aq) ⟶⟶ Ce+3(aq) + Mn+3(aq) Ce+4(aq) + Mn+3(aq) ⟶⟶ Ce+3(aq) + Mn+4(aq) Mn+4(aq) + Tl+1(aq) ⟶⟶ Mn+2(aq) + Tl+3(aq) Identify the intermediate(s) and catalyst(s) if any.
Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction of cerium (IV) with thallium (I) is:
2Ce+4(aq) + Tl+1(aq) ⟶⟶ 2Ce+3(aq) + Tl+3(aq)
The proposed mechanism for this reaction is:
Ce+4(aq) + Mn+2(aq) ⟶⟶ Ce+3(aq) + Mn+3(aq)
Ce+4(aq) + Mn+3(aq) ⟶⟶ Ce+3(aq) + Mn+4(aq)
Mn+4(aq) + Tl+1(aq) ⟶⟶ Mn+2(aq) + Tl+3(aq)
Identify the intermediate(s) and catalyst(s) if any.
Transcribed Image Text:The reaction of cerium (IV) with thallium (I) is:
2Ce+4,
+ TI+1,
2Ce*(aq)
(aq)
(aq)
+ TI+3,
(aq)
The proposed mechanism for this reaction is:
Ce+4,
"(aq)
+ Mn+2,
+ Ce+
a+3,
(aq)
+ Mn*°(aq)
(aq)
+3,
Ce+4,
Ce*“(aq)
+ Mn+3
Ce+3,
(aq)
+ Mn+4,
(aq)
(aq)
Mn*4 (ag) + TI*(ag) > Mn*2(ag) + TI*3 (aq)
+ TI+1,
+ TI+3,
Identify the intermediate(s) and catalyst(s) if any.
O Mn*2(aq) is an intermediate. Mn*
+3,
Mn+4
(aq),
(aq)
are catalysts.
O Mn*3
(aq) is an intermediate. Mn*2
Mn+3,
(aq) are catalysts.
(aq).
O No intermediates. Mn* (aq),
Mn+2,
(aq), Mn*3
(aq) are catalysts.
O Mn** lag) is an intermediate. Mn*2
(aq).
Mn*3,
(aq) are catalysts.
O Mn+4,
Mn*2,
(aq) are intermediates. No catalyst.
(aq).
Mn*3,
(aq).
O Mn** (aq).
Mn+3
(ag) are intermediates. Mn*(ag)
+4
is a catalyst.
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