The reaction A C is first order in the reactant A and is known to go to completion. The product C is colored and absorbs light strongly at 550 nm, while the reactant and intermediates are colorless. A solution of A was prepared, and the absorbance of C at 550 nm was measured as a function of time. (Note that the absorbance of C is directly proportional to its concentration.) Use the following data to determine the half-life of the reaction:

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

I'm not really sure how to approach this problem. I thought you could substitute the half life equation into the integrated equation for first order reactions, but that didn't work.

The reaction A → Cis first order in the reactant A and is known to go to completion.
The product C is colored and absorbs light strongly at 550 nm, while the reactant and
intermediates are colorless. A solution of A was prepared, and the absorbance of C at
550 nm was measured as a function of time. (Note that the absorbance of C is directly
proportional to its concentration.) Use the following data to determine the half-life of
the reaction:
Time (s)
Absorbance
0.000
0.444
10
0.724
1.188
20
100
200
1.200
500
1.200
Transcribed Image Text:The reaction A → Cis first order in the reactant A and is known to go to completion. The product C is colored and absorbs light strongly at 550 nm, while the reactant and intermediates are colorless. A solution of A was prepared, and the absorbance of C at 550 nm was measured as a function of time. (Note that the absorbance of C is directly proportional to its concentration.) Use the following data to determine the half-life of the reaction: Time (s) Absorbance 0.000 0.444 10 0.724 1.188 20 100 200 1.200 500 1.200
Expert Solution
Step 1

Given:

wavelength = 550 nm

Time (s) Absorbance
0 0.000
10 0.444
20 0.724
100 1.188
200 1.200
500 1.200

formula = [C] = Aλ

trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps

Blurred answer
Knowledge Booster
Theories of Reaction Rates
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY