The reaction A C is first order in the reactant A and is known to go to completion. The product C is colored and absorbs light strongly at 550 nm, while the reactant and intermediates are colorless. A solution of A was prepared, and the absorbance of C at 550 nm was measured as a function of time. (Note that the absorbance of C is directly proportional to its concentration.) Use the following data to determine the half-life of the reaction:

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Chapter1: Chemical Foundations
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I'm not really sure how to approach this problem. I thought you could substitute the half life equation into the integrated equation for first order reactions, but that didn't work.

The reaction A → Cis first order in the reactant A and is known to go to completion.
The product C is colored and absorbs light strongly at 550 nm, while the reactant and
intermediates are colorless. A solution of A was prepared, and the absorbance of C at
550 nm was measured as a function of time. (Note that the absorbance of C is directly
proportional to its concentration.) Use the following data to determine the half-life of
the reaction:
Time (s)
Absorbance
0.000
0.444
10
0.724
1.188
20
100
200
1.200
500
1.200
Transcribed Image Text:The reaction A → Cis first order in the reactant A and is known to go to completion. The product C is colored and absorbs light strongly at 550 nm, while the reactant and intermediates are colorless. A solution of A was prepared, and the absorbance of C at 550 nm was measured as a function of time. (Note that the absorbance of C is directly proportional to its concentration.) Use the following data to determine the half-life of the reaction: Time (s) Absorbance 0.000 0.444 10 0.724 1.188 20 100 200 1.200 500 1.200
Expert Solution
Step 1

Given:

wavelength = 550 nm

Time (s) Absorbance
0 0.000
10 0.444
20 0.724
100 1.188
200 1.200
500 1.200

formula = [C] = Aλ

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