Phase Transition Thermodynamic DataformulaTm (°C)AH fus (kJ/mol)E (K-kg/mol)T, (°C)ΔΗvap (kJ/mol)Еъ (К-kg/mol)T. (°C)P (atm)C4489117CBrCIF2-3.6153.7342.0CBRF3CB12F2CBr4-57.767.139.225198.240.892.33.76CCIF3-81.32938.2CL,F2CCI3F-29.7111.8040.823.8198.044.1CC14-22.622.5676.829.82283.544.6CF4CHCIF2-127.9-45.536.9-40.696.449.7CHCI,FCHC139.0178.551.1-63.419.561.1729.24263.354.0CHF3-82.026.247.9CH,Cl,CH2F2CH3CNCH;COC,H5CH3CONH,CH;CO,C,H5-97.24.6049.628.062.4223760.2-51.578.557.581.651.44272.548.25.163.922.82CH3CI-97.76.43-24.0921.40143.1065.9CH3F-78.344.758.0CH3I4.31CH;NO4.25CH;NO22.09CH3OH-97.533.21564.635.210.86239.479.8CH4-182.470.94-161.488.19-82.945.4CO-205.020.833-191.56.04-140.234.5COCI,818256.0CO2-56.569.02-78.5031.173.0CS24627978.0C19H160C10H8C12H11N37.87.458.38 Please use the values in the resources listed below instead of the textbook values.The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¯) in an organic solvent is diffusion controlled.C10H8 + C10H8=C10H8 + C10H8-The reaction is bimolecular and second order. The rate constants are as follows.T/K305295291275k/109 M-1.s-1 2.64 2.21 2.05 1.49Calculate the values of Ea, AH°†, AS°† and AG°† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.]kBT ASot/Re-AH°ł/RT(M1 – m)k =hEa =17.8X kJ•mol-1AH°# =12.9X kJ•mol-1ASot = |-22.3X J-K-1.mol-1AG°# =19.5kJ•mol-1

The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¬) in an organic solvent is diffusion controlled. C10H8¯ + C10H8=C10H8 + C10H8¯ The reaction is bimolecular and second order. The rate constants are as follows. T/K 305 295 291 275 k/109 M-1.s-1 2.64 2.21 2.05 1.49 Calculate the values of Ea, AHo#, ASº† and AGº† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.] k = h kBT Asot/Re-AH®?/RT(M1 – m)

The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¬) in an organic solvent is diffusion controlled. C10H8¯ + C10H8=C10H8 + C10H8¯ The reaction is bimolecular and second order. The rate constants are as follows. T/K 305 295 291 275 k/109 M-1.s-1 2.64 2.21 2.05 1.49 Calculate the values of Ea, AHo#, ASº† and AGº† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.] k = h kBT Asot/Re-AH®?/RT(M1 – m)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: aqueous

Q: 10.7. Nitrogen pentoxide reacts with nitric oxide in the gas phase according to the stoichiometric…

Q: Calculate the rate constant for a reaction using 10.0 mL of 0.156 M hydrogen peroxide diluted to a…

A: The rate of a reaction is defined as the change in concentration of the reactant or the product with…

Q: A unimolecular reaction is observed to have the following rate constants at the indicated…

A: We have given that A unimolecular reaction is observed to have the following rate constants at the…

Q: Use the integrated rate law to calculate time elapsed. The decomposition of nitramide in aqueous…

Q: In aqueous solution buffered at a pH of 6.75 Penicillin G (molecular weight of 334.39 g/mole)…

Q: The following concentration vs time data was obtained for the reaction: A→Products. Determine the…

A: For a first order reaction, the integrated rate law equation is ln [A] = ln [A]o - kt where k is…

Q: The racemization of pinene is a first-order reaction. In the gas phase, the specific rate constant…

A: The question is based on the concept of arrhenius equation. we need to calculate activation energy…

Q: For the gas phase decomposition of acetic anhydride, (CH3CO)20 CH₂=C=O + CH3COOH the rate constant…

A: Information of question

Q: In aqueous solution buffered at a pH of 6.75 Penicillin G (molecular weight of 334.39 g/mole)…

Q: consider the following reaction and data: H2+2ICl→2HCl+I2 Time (s) I2 concentration (M) 5 1.25…

A: Ans The average rate of the formation of the I2 is given by the formula as follows for the reaction…

Q: The second-order rate constants for the reaction of oxygen atoms with aromatic hydrocarbons have…

Q: An unknown inorganic phosphate undergoes first-order dehydration in a drying oven. Initially, the…

Q: T (K) k (year-1) 323 1.17 x 10-8 373 8.10 x 10-5 423 6.93 x 10-2 473 1.42 x 101 523 1.06 x 103 573…

Q: One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) → N2O5(3) +…

Q: The activation energy for the gas phase decomposition of acetic anhydride is 144 kJ. (CH3 CO)2O →…

Q: the rate law for a reaction allows the speed of a reaction to be related to the concentrations of…

A: We are given the iodination of acetone reaction in the presence of an acid catalyst: I2 (aq) +…

Q: The gas phase decomposition of dinitrogen pentoxide at 335 K N2O5(g) 2 NO2(g) + ½ O2(g) is first…

A: Given: Order of the reaction = 1 Rate constant of reaction = 4.70 X 10-3 s-1. Initial concentration…

Q: What is the rate constant (s -1) of a first-order process that has a half-life of 364 s? -1.37 ×…

A: For first order of Reaction the half life period can be written as - t1/2 = 0.692/k Or k =…

Q: Suppose the formation of nitryl fluoride proceeds by the following mechanism: elementary reaction…

A: Overall reaction can be determined by adding all the steps of the reaction mechanism.Rate of…

Q: The decomposition of nitramide in aqueous solution at 25 °C NH,NO2(aq)N20(g) + H20(1) is first order…

A: Given :- NH2NO2(aq) → N2O(g) + H2O(l) Reaction is first order Rate constant = 4.70 × 10-5 s-1…

Q: The average rate of disappearance of N,O5 over

Q: it is known that a drug has a first order elimination rate constant of 0.17 h-1. If this drug is…

A: Answer - First order elimination rate - Although the amount of drug eliminated in a first-order…

Q: what is the form of the integrated rate law which will produce a straight line if the following…

Q: Methane, CH4, is a potent green house gas. The only significant sink for methane is its reaction…

Q: The rate constant for the reaction below was determined to be 3.241x10-5 s-¹ at 800 K. The…

A: For the given reaction,The rate constant (k1) of the given reaction at is . Initial temperature…

Q: The process in which methylisonitrile is converted to acetonitrile was found to follow first order…

A: First order reaction kinetics is the one in which the rate of reaction depends only one of the…

Q: The first order isomerization of cyclopropane has an activation energy of 2.64e5 J/mol and a rate…

Q: The ozonization of pentene in carbon tetrachloride solution at 25 °C C5H10 +O3 → C5 H1003 is first…

A: The order of chemical reaction refers to the exponent to which the concentration of a reactant is…

Q: The activation energy for the gas phase isomerization of cis-1,2-diphenylethene is 179 kJ. cis-C6H5…

A: we have to calculate the temperature when the value of rate constant is 0.00603 s-1

Q: A reaction has a rate constant of 4.8 × 104 M¹ min¹ at 26 °C, and a rate constant of 6.6 × 10-³M-¹…

Q: The following reaction is studied in the laboratory: 3X4 → 12Y8 + 4Z It is determined that at 111…

A: Answer:- This question is answered by using the simple concept of Arrhenius equation which involves…

Q: The rate law for the oxidation of NO was determined to be rate = k[NO]2[0₂]. Which of these…

Q: proposed mechanism for the formation of phosgene (COCl₂) can be written in a simplified form as: Cl₂…

A: In this question, we have to find the rate law corresponding to the proposed mechanism for formation…

Q: For the rearrangement of cyclopropane to propene at 500 °C (CH2)3 CH3 CH=CH2 the following data have…

A: Answer:The average rate of disappearance is equal to the rate of change in concentration of…

Q: Given the following results: Rate of Run Reaction [1] [H₂O₂] (M/s) 1.76 0.358 0.476 4.72 0.358 0.843…

Q: Given the following kinetic data for the first order production of H2O2, what is the rate constant…

Q: The vapor phase dimerization of trifluorochloroethylene to…

Question

100%

Phase Transition Thermodynamic Data
formula
Tm (°C)
AH fus (kJ/mol)
E (K-kg/mol)
T, (°C)
ΔΗ
vap (kJ/mol)
Еъ (К-kg/mol)
T. (°C)
P (atm)
C
4489
117
CBrCIF2
-3.6
153.73
42.0
CBRF3
CB12F2
CBr4
-57.7
67.1
39.2
25
198.2
40.8
92.3
3.76
CCIF3
-81.3
29
38.2
CL,F2
CCI3F
-29.7
111.80
40.8
23.8
198.0
44.1
CC14
-22.62
2.56
76.8
29.82
283.5
44.6
CF4
CHCIF2
-127.9
-45.5
36.9
-40.6
96.4
49.7
CHCI,F
CHC13
9.0
178.5
51.1
-63.41
9.5
61.17
29.24
263.3
54.0
CHF3
-82.0
26.2
47.9
CH,Cl,
CH2F2
CH3CN
CH;COC,H5
CH3CONH,
CH;CO,C,H5
-97.2
4.60
49.6
28.06
2.42
237
60.2
-51.5
78.5
57.5
81.65
1.44
272.5
48.2
5.16
3.92
2.82
CH3CI
-97.7
6.43
-24.09
21.40
143.10
65.9
CH3F
-78.3
44.7
58.0
CH3I
4.31
CH;NO
4.25
CH;NO2
2.09
CH3OH
-97.53
3.215
64.6
35.21
0.86
239.4
79.8
CH4
-182.47
0.94
-161.48
8.19
-82.9
45.4
CO
-205.02
0.833
-191.5
6.04
-140.2
34.5
COCI,
8
182
56.0
CO2
-56.56
9.02
-78.50
31.1
73.0
CS2
46
279
78.0
C19H160
C10H8
C12H11N
37.8
7.45
8.38

Please use the values in the resources listed below instead of the textbook values.
The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¯) in an organic solvent is diffusion controlled.
C10H8 + C10H8=C10H8 + C10H8-
The reaction is bimolecular and second order. The rate constants are as follows.
T/K
305
295
291
275
k/109 M-1.s-1 2.64 2.21 2.05 1.49
Calculate the values of Ea, AH°†, AS°† and AG°† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.]
kBT ASot/Re-AH°ł/RT(M1 – m)
k =
h
Ea =
17.8
X kJ•mol-1
AH°# =
12.9
X kJ•mol-1
ASot = |-22.3
X J-K-1.mol-1
AG°# =
19.5
kJ•mol-1

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step 6

Step 7

Trending now

This is a popular solution!

Step by step

Solved in 7 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

16) The reaction (C2H5)2(NH2) + 12 (C2H5)2(N2) + 2HI gives the following data. Expt Initial(C2H5)2(NH2) mol L-1 Initial 12 mol L-1 Initial rate of formation of (C2H5)2(N2) mol L-1min-1 1 0.015 0.015 3.15 x 10-1 2 0.015 0.045 9.45x 10-1 3 0.030 0.045 18.9 x 10-1 a) Determine the order of the reaction with respect to each reactant. Explain how you arrived at each answer. (Show your method) b) What is the overall order of the reaction? c) Write the rate law expression. d) Calculate the rate constant, k and provide the proper units. e) If (C2H5)2(N2) is formed at a rate of 9.45 M/s in experiment 3, what is the rate of appearance of HI? f) In experiment 3, assuming it goes to completion, if all of [(C2H5)2(NH2) ] is reacted, what would be the amount of 12 remaining?
In aqueous solution buffered at a pH of 6.75 Penicillin G (molecular weight of 334.39 g/mole) undergoes hydrolysis via a pseudo first order reaction that has an activation energy of 77.3 kJ/mole and a pseudo first order rate constant of 1.58 x 10-7 s-1 at 30°C. If a vial of Penicillin G containing 5,000,000 units is stored under the conditions above, how many days will it take for 10% of the drug to hydrolyze?
The gas phase decomposition of dinitrogen pentoxide at 335 K N205(g)2 NO2(g) + ½ 02(g) is first order in N205. During one experiment it was found that when the initial concentration of N205 was 7.50×10-2 M, the concentration of N205 dropped to 2.09×10-2M after 198 s had passed. Based on this experiment, the rate constant for the reaction is || IS s-1.
In the unimolecular gas phase reaction kinetics, what is the rate equation for the deactivation of the energized molecule A*? d[A*]/dt=-k'a[A] [A*] d[A*]/dt=ka[A]? O d[A*]/dt=-k½[A*] d[A*]/dt=k[A*]
In aqueous solution buffered at a pH of 6.75 Penicillin G (molecular weight of 334.39 g/mole) undergoes hydrolysis via a pseudo first order reaction that has an activation energy of 77.3 kJ/mole and a pseudo first order rate constant of 1.58 x 10-7 s-1 at 30°C. What is the half life (in days) of Penicillin G under the conditions described?
Use the data given below to find rate constant. Then derive the rate law for this reaction. Show your work in a separate sheet. S20g2-(ag) + 31(ag) 2 SO42-(g) +13 (a4) [S20g2-i (M) [[h (M) Initial Rate (M/s) 0.30 0.42 4.54 0.44 0.42 6.65 0.44 0.21 3.33 Rate = [36 M -1s-1IS 20 8 2-1] [86 M -25-1S 20 82-12 Rate = Rate = [120 M -25-1S 20 82121] Rate = [195 M -3s 1S 20 8 21211-2
Can I get the solution of the problem?
The rate constant for the reaction of nitrogen with oxygen was determined at four temperatures. N2(g) + O2(g) T(K) 2NO(g) k (cm3/molecule⚫s) 250 7.18 x 10-8 275 1.36 x 10-7 300 2.31 x 10-7 325 3.46 x 10-7 3rd attempt Part 1 (1 point) Plot these data to calculate the activation energy of the reaction. kJ/mol Part 2 (1 point) Plot these data to calculate the frequency factor A for the reaction. cm3/molecules
Please don't provide handwritten solution ....