One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) → N2O5(3) + O2l3). Assume that a species with the formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate - k[NO2][031. Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(3) + O3(g) – NO3(g) + Ozlg) (fast) 4NO;G) – 2N¿O5(3) + O23) (slow) NO:G) + Oglg) → NO3(s) + O2lg) (slow) NO3(9) + NO2(g) – N2Os(G) (fast) NO2(3) + O3lg) → NO3lg) + O2ls) (fast) NO3(g) + NO2(3) – N;Os(3) (slow) NO2(3) + O3lg) → NOJG) + Ozlg) (slow) 4NO33) – 2N2O5(g) + O2lg) (fast)

One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) → N2O5(3) + O2l3). Assume that a species with the formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate - k[NO2][031. Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(3) + O3(g) – NO3(g) + Ozlg) (fast) 4NO;G) – 2N¿O5(3) + O23) (slow) NO:G) + Oglg) → NO3(s) + O2lg) (slow) NO3(9) + NO2(g) – N2Os(G) (fast) NO2(3) + O3lg) → NO3lg) + O2ls) (fast) NO3(g) + NO2(3) – N;Os(3) (slow) NO2(3) + O3lg) → NOJG) + Ozlg) (slow) 4NO33) – 2N2O5(g) + O2lg) (fast)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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