The molar enthalpy of vaporization of benzene at its normal boiling point (80.09°C) is 30.72 kJ/mol.Assuming that AvapH and AvapS stay constant at their values at 80.09°C, calculate the value ofAvapG at 75.0°C, 80.09°C, and 85.0°C.Hint: Remember that the liquid and vapor phases will be in equilibrium at the normal boiling point.

To calculate ΔvapG at different temperatures, we use the Gibbs free energy equation: ΔvapG =ΔvapH…

Answered: The molar enthalpy of vaporization of…

Physics for Scientists and Engineers: Foundations and Connections

1st Edition

ISBN:9781133939146

Author:Katz, Debora M.

Publisher:Katz, Debora M.

Chapter19: Temperature, Thermal Expansion And Gas Laws

Section: Chapter Questions

Problem 61PQ

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One process for decaffeinating coffee uses carbon dioxide ( M=44.0 g/mol) at a molar density of about 14,0 mol/m3 and a temperature of about 60 . (a) Is CO2 a solid, liquid, gas, or supercritical fluid under those conditions? (b) The van der Waals constants for carbon dioxide are a=0.3658 Pa m6/mol2 and b=4.286105 m3/mol. Using the van der Waals equation, estimate pressure of CO2 at that temperature and density. `
On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?
How many moles are there in (a) 0.0500 g of N2 gas (M = 28.0 g/mol)? (b) 10.0 g of CO2 gas (M = 44.0 g/mol)? (c) How many molecules are present in each case?
If the average kinetic energy of the molecules in an ideal gas initially at 20C doubles, what is the final temperature of the gas? (5.6) (a) 10C (b) 40C (c) 313C (d) 586C
A 0.500-m3 container holding 3.00 mol of ozone (O3) is kept at a temperature of 250 K. Assume the molecules have radius r = 2.50 1010 m. What are the a. mean free path and b. mean free time between collisions for an ozone molecule in the container?
A sealed cubical container 20.0 cm on a side contains a gas with three times Avogadros number of neon atoms at a temperature of 20.0C. (a) Find the internal energy of the gas. (b) Find the total translational kinetic energy of the gas. (c) Calculate the average kinetic energy per atom, (d) Use Equation 10.13 to calculate the gas pressure. (e) Calculate the gas pressure using the ideal gas law (Eq. 10.8).
Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.
A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P21.65). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state, (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally, (f) Find Q, W, and Eint for each of the processes, (g) For the whole cycle A B C A, find Q, W, and Eint.
A 40.0-g projectile is launched by the expansion of hot gas in an arrangement shown in Figure P12.4a. The cross sectional area of the launch tube is 1.0 cm2, and the length that the projectile travels down the tube after starting from rest is 52 cm. As the gas expands, the pressure varies as shown in Figure P12.4b. The values for the initial pressure and volume are P1 = 11 105 Pa and Vi = 8.0 cm3 while the final values are Pf = 1.0 105 Pa and Vf = 8.0 cm3. Friction between the projectile and the launch tube is negligible, (a) If the projectile is launched into a vacuum, what is the speed of the projectile as it leaves the launch tube? (b) If instead the projectile is launched into air at a pressure of 1.0 105 Pa. what fraction of the work done by the expanding gas in the tube is spent by the projectile pushing air out of the way as it proceeds down tile tube?
Consider water at 0C and initially at some pressure just below the critical pressure. Its pressure is then lowered to a value near zero while the temperature is held constant. Hint: Consult Figure 20.17. a. Describe the phases that water passes through during this process. b. If the curve between the solid phase and the liquid phase sloped upward and to the right as it does for carbon dioxide, how would your answer to part (a) change?
(a) Using data from the previous problem, find the mass of nitrogen, oxygen, and argon in 1 mol of dry air. The molar mass of N2 is 28.0 g/mol, that of O2 is 32.0 g/mol, and that of argon is 39.9 g/mol. (b) Dry air is mixed with pentane 5 H12, molar mass 72.2 g/mol), an important constituent of gasoline, in an air-fuel ratio of 15:1 by mass (roughly typical for car engines). Find the partial pressure of pentane in this mixture at an overall pressure of 1.00 atm.
Using a numerical integration method such as Simpson's rule, find the fraction of molecules in a sample of oxygen gas at a temperature of 250 K that have speeds between 100 m/s and 150 m/s. The molar mass of oxygen (O2) is 32.0 g/mol. A precision to two significant digits is enough.

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