The mass spectrum of compound A shows the molecular ion at m/z 85, an M + 1 peak at m/z 86 of approximately 6% abundance relative to M, and an M+2 peak at m/z 87 of less than 0.1% abundance relative to M. Assuming that compound A has only C, H, and one N atoms, determine the molecular formula, and then draw a possible structure if compound A has IR absorption at 1620-1680 cm but not at 3010-3090 cm-1 • You do not have to consider stereochemistry.

The mass spectrum of compound A shows the molecular ion at m/z 85, an M + 1 peak at m/z 86 of approximately 6% abundance relative to M, and an M+2 peak at m/z 87 of less than 0.1% abundance relative to M. Assuming that compound A has only C, H, and one N atoms, determine the molecular formula, and then draw a possible structure if compound A has IR absorption at 1620-1680 cm but not at 3010-3090 cm-1 • You do not have to consider stereochemistry.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Analysis of a sweet-smelling, neutral compound of carbon, hydrogen and oxygen produced the following results: %C = 54.5; %H = 9.1. From its mass spectrum, the molecular ion had a mass/charge ratio of 88. Its infra-red spectrum showed a prominent peak at 1735 cm–1. Figure below shows the NMR spectrum of the compound. Which of the following is this compound? A. 3-hydroxybutanalB. Methyl propionateC. Ethyl acetateD. 2-methylpropanoic acidE. Methoxyacetone
Propose a possible structure for the compound represented by IR and mass spectra.
A student performed a series of reactions and obtained the spectral data provided. The reaction sequence is shown below.. What are the structures for A, B, C, and D? Compound B NMR (relative integrated areas below peaks) CH;CH,O°N 1. BHTHF N-bromosuccnimide A CH;CH,OH B 2. H,O,/OH- D hv reflux Compound A NMR (relative integrated areas below peaks) PPM 5 Compound B IR INFRARED SPECTRUM PPM 5 1 6 0.8 Compound A IR INFRARED SPECTRUM 0.6 0.8 0.4 0.4 0.2- 3000 2000 Wavenumber (cm-1) 1000 The MS of compound B shows an M+ peak at 198 and an M+2 peak at 200 with a relative abundance of 1:0.97 2000 Wavenumber (cm-1) 3000 1000 Transmitance Relative Transmittance
The infrared spectrum of a compound has a strong absorption at 1669 cm. The mass spectrum of the compound is provided below. What is the structure of the compound? 100 - 80 - 60 40 20 0- 50 75 100 125 m/z OH NH2 Relative Intensity
Use the 1H NMR and IR spectra given below to identify the structure of compound B (molecular formula C4H8O2).
14. Which among the given compounds would be most consistent with the following information? MS PEAKS: m/z 120, m/z 105, and m/z 77 ¹H NMR: singlet at 2.1 ppm AND multiplet at 7.1 ppm IR: strong peak at 1687 cm ¹ I IV II V III
The NMR spectra for compound 1 were acquired in a 7.5 mg / 0.6 mL solution ofCDCl3 . The 1H and 13C peaks are also listedbelow. Provide a full analysis of the NMR spectra for compound 1. correct assignment of NMR spectra of both 13C spectra. correct rationalisation of 13C spectrum1H NMR (400 MHz, CDCl3) δ 7.73 (d, J = 9.5 Hz, 1H), 7.56 (ddd, J = 8.5, 7.5, 1.6 Hz, 1H),7.51 (dd, J = 7.5, 1.6 Hz, 1H), 7.36 (d, J = 8.5 Hz, 1H), 7.30 (dd, J = 8.5, 7.5 Hz, 1H), 6.45(d, J = 9.5 Hz, 1H).13C NMR (101 MHz, CDCl3) δ 160.79, 154.09, 143.43, 131.85, 127.87, 124.44, 118.86,116.94, 116.74.Note: There are two carbon peaks in the 13C spectrum that are so close together that they are not differentiable at the resolution in this experiment. you should be able to assign these peaks to one of two carbon atoms in 1.
A compound displays a prominent peak at 3400 cm¹ in its IR spectrum. The mass spectrum has a molecular ion with m/z of 74. The base peak is at m/z = 45. Draw a structure that best fits this data. Drawing I Atoms and
Predict the structure of the compound using the information below. From IR Spectra: Broad peak at 3500-3200 cm-1 Medium peak at 750 cm-1 From Mass Spectra M+ = 108 M+2 = 110 (with 3:1 peak ratio) From Proton NMR Spectra See attached picture.