The irreversible reaction, A + B → C, in liquid phase is carried out in a non-isothermal 200 L batch reactor. The reaction is first order with respect to both reactants. The reactor is loaded with A and B, whose concentrations are CAo=0.5 mol/L and CBo=0.6 mol/L. The heat of reaction is -15 kJ/mol and is independent of temperature. The initial temperature of the reactor of 27 ºC is obtained by passing a fluid through the reactor jacket. The average heat capacities are: CpA=CpB=65J/(mol K) and CpC=150 J/(mol K). The global heat exchange coefficient and the heat exchange area are related by UxA= 50 J/(sK). The speed constant is given by: a) Determine the reaction time required to obtain a conversion of 80%;

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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The irreversible reaction, A + B → C, in liquid phase is carried out in a non-isothermal 200 L batch reactor. The reaction is first order with respect to both reactants. The reactor is loaded with A and B, whose concentrations are CAo=0.5 mol/L and CBo=0.6 mol/L. The heat of reaction is -15 kJ/mol and is independent of temperature. The initial temperature of the reactor of 27 ºC is obtained by passing a fluid through the reactor jacket. The average heat capacities are: CpA=CpB=65J/(mol K) and CpC=150 J/(mol K). The global heat exchange coefficient and the heat exchange area are related by UxA= 50 J/(sK). The speed constant is given by:

a) Determine the reaction time required to obtain a conversion of 80%;

[20000 ( 1
L
k = 5 x 10-3exp
in
8,314
mol s
Transcribed Image Text:[20000 ( 1 L k = 5 x 10-3exp in 8,314 mol s
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