The initial rates for the following two elimination reactions were measured under different 9. concentrations of the electrophiles and bases (H2O in the top reaction, KOCH2CH3 in the bottom reaction; all data is presented in the two tables. For each reaction, top and bottom, does the data suggest an El or E2 reaction pathway (rates are all 10* units)? Explain. Write the rate equations for each reaction. Trial Number [R-OCH1 (H01 Rate (M/s) 0.010 M 0.45 M 9.50 x 10- 1 HO 0.020 M 0.45 M 1.85 x 10 3 CH,CN, OCH, 0.22 M 1.85 x 10- 3 0.020 M Trial Number IR-Br] TKOCH CHal Rate (M/s) 1.0 M 1.0 M 2.35 x 10 1 2 0.50 M 0.50 M 5.9 x 10 + KOCH,CH, CH,CH,OH 0.50 M 1.0 M 1.20 x 106

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9.
The initial rates for the following two elimination reactions were measured under different
concentrations of the electrophiles and bases (H2O in the top reaction, KOCH2CH3 in the bottom
reaction; all data is presented in the two tables. For each reaction, top and bottom, does the data suggest
an El or E2 reaction pathway (rates are all 10* units)? Explain. Write the rate equations for each
reaction.
Trial Number [R-OCH.]
[H,0]
Rate (M/s)
0.010 M
0.45 M
9.50 X 10-4
HO
2
0.020 M
0.45 M
1.85 x 10 3
CH,CN, H
OCH,
0.22 M
1.85 x 10-
3
0.020 M
Trial Number R-Br]
[KOCH,CHal
Rate (M/s)
6
1.0 M
1.0 M
2.35 X 10
Br
0.50 M
0.50 M
5.9 x 10*
+ KOCH,CH,
CH,CH,OH
3
0.50 M
1.0 M
1.20 x 10
Top Reaction:
Bottom Reaction:
Transcribed Image Text:9. The initial rates for the following two elimination reactions were measured under different concentrations of the electrophiles and bases (H2O in the top reaction, KOCH2CH3 in the bottom reaction; all data is presented in the two tables. For each reaction, top and bottom, does the data suggest an El or E2 reaction pathway (rates are all 10* units)? Explain. Write the rate equations for each reaction. Trial Number [R-OCH.] [H,0] Rate (M/s) 0.010 M 0.45 M 9.50 X 10-4 HO 2 0.020 M 0.45 M 1.85 x 10 3 CH,CN, H OCH, 0.22 M 1.85 x 10- 3 0.020 M Trial Number R-Br] [KOCH,CHal Rate (M/s) 6 1.0 M 1.0 M 2.35 X 10 Br 0.50 M 0.50 M 5.9 x 10* + KOCH,CH, CH,CH,OH 3 0.50 M 1.0 M 1.20 x 10 Top Reaction: Bottom Reaction:
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