The following spectral data are provided for a compound with a molecular formula CHaNO;: IR (solution in CHCI), 500 MHz 'H NMR, 125.8 MHz "C NMR, DEPT-90, DEPT-135, COSY, HMQC, HMBC, TOCSY (150 ms mixing time) and NOESY. Also included are select regions of the HSQC-TOCSY spectra with increasing mixing times. All NMR spectra were measured in CDCI, solution. Using these data, determine the structure of the compound and assign all of the H and C resonances to their respective atoms in the structure. Make sure to determine the stereochemistry of the compound and to clearly assign 'H resonances to the appropriate diastereotopic protons.

The following spectral data are provided for a compound with a molecular formula CHaNO;: IR (solution in CHCI), 500 MHz 'H NMR, 125.8 MHz "C NMR, DEPT-90, DEPT-135, COSY, HMQC, HMBC, TOCSY (150 ms mixing time) and NOESY. Also included are select regions of the HSQC-TOCSY spectra with increasing mixing times. All NMR spectra were measured in CDCI, solution. Using these data, determine the structure of the compound and assign all of the H and C resonances to their respective atoms in the structure. Make sure to determine the stereochemistry of the compound and to clearly assign 'H resonances to the appropriate diastereotopic protons.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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