Given the information about the unknown: Unknown: MP: 101-106 oC White solid IR: 2837, 1701, 1602, 1391, 1139 cm-1 ** Using the Reference sheet, The IR and the given H-NMR, and C-NMR. Deduce, what the unknown is. Please give the name of uknown
Given the information about the unknown: Unknown: MP: 101-106 oC White solid IR: 2837, 1701, 1602, 1391, 1139 cm-1 ** Using the Reference sheet, The IR and the given H-NMR, and C-NMR. Deduce, what the unknown is. Please give the name of uknown
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Given the information about the unknown:
Unknown:
MP: 101-106 oC
White solid
IR: 2837, 1701, 1602, 1391, 1139 cm-1
**
Using the Reference sheet, The IR and the given H-NMR, and C-NMR. Deduce, what the unknown is. Please give the name of uknown
![Suzuki Cross Coupling Reaction
Synthesis of an Unsymmetrical Biaryl via a Suzuki Cross Coupling Reaction'
Experimental Goals:
Perform the cross coupling reaction from two unknown coupling partners and isolate the product.
Determine the structure of the product from its IR and NMR spectra and melting point, and in tum
determine the starting materials.
B(OH)2
Pd(OAc)2, PPH3
аq NazCOs
Br
R'
n-PrOH
R = H, CH3
R' = H, CH3, OCH3
R"
Name
Structure
mp
1-biphenyl-4-yl-ethanone
120-121°C*
CHS
1-biphenyl-4-yl-ethanol
96-98 °C
CH3
biphenyl-4-carbaldehyde
60-63 "C
OH
4-phenyl-benzyl alcohol
104-105 °C"
H.
1-(4"-methyl-biphenyl-4-yl) ethanone
119-120 °C
CH3
OH
1-(4'methyl-biphenyl-4-yl)-ethanol
95-96 "C"
CH3
4(4'-methylphenyl)-benzaldehyde
107 °C"
он
4'-methyl-(biphenyl-4-yl)-methanol
100-101 "C
H.
1-(4"-methoxy-biphenyl-4-yl)-ethanone
Meo
153-154 "C2
CH3
OH
1-(4'-methoxy-biphenyl-4-yl)-ethanol
Meo
120-122 °C
CH3
4'-methoxy-biphenyl-4-carbaldehyde
Meo
105-106 "C4
H.
OH
4'-methoxy-biphenyl-4-yl-methanol
162-163 "C
Meo](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F33367630-baef-4794-a3c7-3f7d1dfa9a18%2Fec3322ef-2165-482c-9632-672e6ad20baa%2Fvxfdpx_processed.png&w=3840&q=75)
Transcribed Image Text:Suzuki Cross Coupling Reaction
Synthesis of an Unsymmetrical Biaryl via a Suzuki Cross Coupling Reaction'
Experimental Goals:
Perform the cross coupling reaction from two unknown coupling partners and isolate the product.
Determine the structure of the product from its IR and NMR spectra and melting point, and in tum
determine the starting materials.
B(OH)2
Pd(OAc)2, PPH3
аq NazCOs
Br
R'
n-PrOH
R = H, CH3
R' = H, CH3, OCH3
R"
Name
Structure
mp
1-biphenyl-4-yl-ethanone
120-121°C*
CHS
1-biphenyl-4-yl-ethanol
96-98 °C
CH3
biphenyl-4-carbaldehyde
60-63 "C
OH
4-phenyl-benzyl alcohol
104-105 °C"
H.
1-(4"-methyl-biphenyl-4-yl) ethanone
119-120 °C
CH3
OH
1-(4'methyl-biphenyl-4-yl)-ethanol
95-96 "C"
CH3
4(4'-methylphenyl)-benzaldehyde
107 °C"
он
4'-methyl-(biphenyl-4-yl)-methanol
100-101 "C
H.
1-(4"-methoxy-biphenyl-4-yl)-ethanone
Meo
153-154 "C2
CH3
OH
1-(4'-methoxy-biphenyl-4-yl)-ethanol
Meo
120-122 °C
CH3
4'-methoxy-biphenyl-4-carbaldehyde
Meo
105-106 "C4
H.
OH
4'-methoxy-biphenyl-4-yl-methanol
162-163 "C
Meo
![Unknown:
MP: 101-106 °C
White solid
IR: 2837, 1701, 1602, 1391, 1139 cm-l|
Su Cool
EEREEERR
|梦罗
e 4, 5 A3
ia s O S e AS 25 S
45
25 28
H-NMR
200
180
180
140
120
PPM
C-NMR](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F33367630-baef-4794-a3c7-3f7d1dfa9a18%2Fec3322ef-2165-482c-9632-672e6ad20baa%2F0gwwg6i_processed.png&w=3840&q=75)
Transcribed Image Text:Unknown:
MP: 101-106 °C
White solid
IR: 2837, 1701, 1602, 1391, 1139 cm-l|
Su Cool
EEREEERR
|梦罗
e 4, 5 A3
ia s O S e AS 25 S
45
25 28
H-NMR
200
180
180
140
120
PPM
C-NMR
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