سلا 4000 100 80 IR Spectrum (liquid film) 60 40 20 % of base peak 40 3000 13C NMR Spectrum (50.0 MHz, CDCI, solution) proton decoupled DEPT CH₂ CH₂ CH 200 80 ¹H NMR Spectrum (200 MHz, CDCI, solution) 4.8 2000 107/109 L 120 v (cm¹) 160 1740 152/154 m/e 160 1600 4.0 ppm M** 180/182 L expansions 1200 120 800 Mass Spectrum 200 240 280 2.0 C5HgBrO₂ l solvent 1 80 1.2 ppm 40 IL 1 0 8 (ppm) TMS 1

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Provide the structure of the organic molecule that would give rise to these spectra. (Include: degree of unsaturation, present functional groups, assignment of all 1H and 13C NMR peaks by labeling each peak with specific atoms in the structure).
IR Spectrum
(liquid film)
4000
100
80
60
40
20
ae
40
3000
13C NMR Spectrum
(50.0 MHz, CDCI, solution)
proton decoupled
DEPT CH₂ CH₂ CH
200
80
¹H NMR Spectrum
(200 MHz, CDCI, solution)
4.8
2000
107/109
1740
V (cm¹)
160
120 160
m/e
1600
M+
152/154 180/182
4.0 ppm
expansions
www
120
1200
200 240
2.0
800
Mass Spectrum
C5HgBrO₂
280
solvent
80
*
I
1.2 ppm
40
0
1
8 (ppm)
TMS
1
Transcribed Image Text:IR Spectrum (liquid film) 4000 100 80 60 40 20 ae 40 3000 13C NMR Spectrum (50.0 MHz, CDCI, solution) proton decoupled DEPT CH₂ CH₂ CH 200 80 ¹H NMR Spectrum (200 MHz, CDCI, solution) 4.8 2000 107/109 1740 V (cm¹) 160 120 160 m/e 1600 M+ 152/154 180/182 4.0 ppm expansions www 120 1200 200 240 2.0 800 Mass Spectrum C5HgBrO₂ 280 solvent 80 * I 1.2 ppm 40 0 1 8 (ppm) TMS 1
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