Information: Each spectra below was obtained from a pure compound. Mass Spectrum parent peaks (M) are listed for all examples. IR peaks listed are strong (s) unless otherwise indicated for signals above 1500 cm³¹ ¹H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants (J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a "zoom-in" on an important part of the spectrum. Mass Spectrometry (not shown): [M] = 88 m/z Infrared Spectroscopy (not shown): 3376, 2967, 2927 cm¹ ¹H Nuclear Magnetic Resonance. 5 1H 1³C Nuclear Magnetic Resonance. 80 8 60 50 3 PPM 40 PPM 30 2H 6H 3H 20 10

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Information:** Each spectrum below was obtained from a pure compound. Mass Spectrum parent peaks (M) are listed for all examples. IR peaks listed are strong (s) unless otherwise indicated for signals above 1500 cm⁻¹. 

¹H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants (J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a “zoom-in” on an important part of the spectrum.

**Mass Spectrometry (not shown):** [M] = 88 m/z

**Infrared Spectroscopy (not shown):** 3376, 2967, 2927 cm⁻¹

**¹H Nuclear Magnetic Resonance:**

- A graph is displayed with the chemical shift (PPM) on the x-axis ranging from 0 to 5 PPM.
- Signals:
  - A singlet (s) at approximately 3.4 PPM, integrating to 1 hydrogen.
  - A quartet (q) at around 1.2 PPM, integrating to 2 hydrogens.
  - A triplet (t) at about 0.9 PPM, integrating to 3 hydrogens.

**¹³C Nuclear Magnetic Resonance:**

- A graph is shown with the chemical shift (PPM) on the x-axis ranging from 0 to 80 PPM.
- Peaks are observed at:
  - Approximately 13, 25, 41, and 72 PPM.
Transcribed Image Text:**Information:** Each spectrum below was obtained from a pure compound. Mass Spectrum parent peaks (M) are listed for all examples. IR peaks listed are strong (s) unless otherwise indicated for signals above 1500 cm⁻¹. ¹H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants (J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a “zoom-in” on an important part of the spectrum. **Mass Spectrometry (not shown):** [M] = 88 m/z **Infrared Spectroscopy (not shown):** 3376, 2967, 2927 cm⁻¹ **¹H Nuclear Magnetic Resonance:** - A graph is displayed with the chemical shift (PPM) on the x-axis ranging from 0 to 5 PPM. - Signals: - A singlet (s) at approximately 3.4 PPM, integrating to 1 hydrogen. - A quartet (q) at around 1.2 PPM, integrating to 2 hydrogens. - A triplet (t) at about 0.9 PPM, integrating to 3 hydrogens. **¹³C Nuclear Magnetic Resonance:** - A graph is shown with the chemical shift (PPM) on the x-axis ranging from 0 to 80 PPM. - Peaks are observed at: - Approximately 13, 25, 41, and 72 PPM.
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