**1H NMR Analysis of 2-Propanol (C₃H₈O)****Question 17:**The partial chemical structure and ¹H NMR spectrum of 2-propanol (C₃H₈O) are shown. Draw in the hydrogen atoms and label them with a subscript that corresponds to the labeled peaks in the ¹H NMR spectrum. Provide a brief rationale for your structural assignments.### NMR Spectrum Details:- **Peak 1:** - Chemical shift: 4.01 ppm - Integration: 1H - Splitting pattern: Septet- **Peak 2:** - Chemical shift: 2.16 ppm - Integration: 1H - Splitting pattern: Singlet- **Peak 3:** - Chemical shift: 1.20 ppm - Integration: 6H - Splitting pattern: Doublet### Structure of 2-Propanol:- Hydrogen atoms labeled as H₁, H₂, and H₃: ``` H₁ | H₃ - C - H₃ | H₂ - C - C - H₃ | H₃ ```### Rationale for Peak Assignments:- **Peak 1 (4.01 ppm):** Assigned to H₂, which is the hydrogen on the carbon bonded to the oxygen. This environment leads to a higher chemical shift due to the electron-withdrawing effect of the oxygen. The septet pattern results from coupling with the adjacent six hydrogen atoms (H₃).- **Peak 2 (2.16 ppm):** Assigned to OH proton. The singlet pattern arises because this proton typically does not couple with adjacent protons.- **Peak 3 (1.20 ppm):** Assigned to H₃, the hydrogens on the terminal methyl groups. The lower chemical shift is typical for hydrogens far from electronegative atoms. The doublet arises from coupling with a single adjacent hydrogen (H₂).**Graph Explanation:**The NMR spectrum graph shows intensity (y-axis) versus chemical shift in ppm (x-axis). Each peak corresponds to distinct hydrogen environments within the 2-propanol molecule, with integration values indicating the number of

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17) The partial chemical structure and ¹H NMR spectrum of 2-propanol (C3H80) are in the hydrogen atoms and label them with a subscript that corresponds to the labeled peaks in the ¹H NMR spectrum. Provide a brief rationale for your structural assignments. 11 10 9 8 7 6 Peak 1: 4.01 ppm 1H Septet T 5 1 4 Peak 2: 2.16 ppm 1H Singlet 3 Peak 3: 1.20 ppm 6H Doublet HSP-03-214 ppm Rationale for peak assignments in structure: 2 1 0 Draw in labeled hydrogen atoms (H₁, H₂, H3) and assign them to peaks 1-3 H 2 C Structure of 2-propanol -H 11.1

17) The partial chemical structure and ¹H NMR spectrum of 2-propanol (C3H80) are in the hydrogen atoms and label them with a subscript that corresponds to the labeled peaks in the ¹H NMR spectrum. Provide a brief rationale for your structural assignments. 11 10 9 8 7 6 Peak 1: 4.01 ppm 1H Septet T 5 1 4 Peak 2: 2.16 ppm 1H Singlet 3 Peak 3: 1.20 ppm 6H Doublet HSP-03-214 ppm Rationale for peak assignments in structure: 2 1 0 Draw in labeled hydrogen atoms (H₁, H₂, H3) and assign them to peaks 1-3 H 2 C Structure of 2-propanol -H 11.1

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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