The following NMR corresponds to the molecule depicted below ran without reference. Assign the carbons to the peaks of the spectrum. Do this approximating the shift based on the atoms the Cs are attached to. The question & answer options are attached.
The following NMR corresponds to the molecule depicted below ran without reference. Assign the carbons to the peaks of the spectrum. Do this approximating the shift based on the atoms the Cs are attached to. The question & answer options are attached.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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The following NMR corresponds to the molecule depicted below ran without reference. Assign the carbons to the peaks of the spectrum. Do this approximating the shift based on the atoms the Cs are attached to.
The question & answer options are attached.

Transcribed Image Text:The image displays a nuclear magnetic resonance (NMR) spectrum, likely a Carbon-13 NMR, given the parts-per-million (ppm) scale. The spectrum features several peaks corresponding to different carbon environments in the molecule depicted at the top.
### Molecular Structure:
- The molecule shown contains a silane group (Si) bonded to various carbon atoms. It includes a hydroxyl group (HO) and is labeled:
- Carbon 1: adjacent to the hydroxyl group.
- Carbon 2: linked to Si.
- Carbon 3: branching from Si.
### NMR Spectrum Details:
- **X-Axis (ppm scale):** Ranges from about 100 ppm to -20 ppm. This scale is typical for Carbon-13 NMR.
- **Peaks:**
- A peak at **77 ppm**, likely corresponding to a carbon environment, such as CDCl3, the common solvent peak.
- A peak at **59 ppm**, possibly associated with Carbon 2 or a similar environment.
- A peak at **21 ppm**, which might correspond to Carbon 3.
- A peak at **-2 ppm** may be related to TMS (Tetramethylsilane), used as a reference standard.
### Dropdown Selection:
The dropdown menu allows selecting possible assignments for the peaks:
- Options include CDCl3, Carbon 3, MeOD, TMS, Carbon 2, and Carbon 1, assisting in attributing each peak to its respective carbon type in the structure.
This NMR spectrum provides critical information for determining the molecular structure by identifying the chemical environment of the carbon atoms in the compound.
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