4) Contains C,H,N MASS SPECTRUM 100 80 60 40 20 0.0 10 20 30 40 50 60 m/z NIST Chemistry WebBook (https://webbook.nist.gov/chemistry) Rel. Intensity H 70 80
4) Contains C,H,N MASS SPECTRUM 100 80 60 40 20 0.0 10 20 30 40 50 60 m/z NIST Chemistry WebBook (https://webbook.nist.gov/chemistry) Rel. Intensity H 70 80
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter9: Atomic Absorption And Atomic Fluorescence Spectrometry
Section: Chapter Questions
Problem 9.6QAP
Related questions
Question
FOR EACH SPECTRUM BELOW,
• IDENTIFY (ASSIGN) THE MOLECULAR ION PEAK AND THE MOLECULAR WT OF THE COMPOUND. ( KEEP IN MIND THAT SOMETIMES THE MOLECULAR ION MAY NOT BE PRESENT, ESPECIALLY FOR LARGE AND BRANCHED CHAIN MOLECULES WITH NO RINGS SINCE THEY CAN FORM STABLE CATION FRAGMENTS)
• IDENTIFY THE BASE PEAK AND DRAW STRUCTURE FOR IT ( ASSIGNING THE PEAKS).)
• ASSIGN STRUCTURES FOR OTHER PROMINENT FRAGMENTS IF POSSIBLE
• BASED ON THIS, SUGGEST A STRUCTURE FOR THE COMPOUND THAT IS CONSISTENT WITH THE DEGREE OF UNSATURATION OF THE COMPOUND
INDICATE THE BONDS THAT FRAGMENT, RESULTING IN THE OBSERVED MASS SPECTRAL FRAGMENTS
![4) Contains C,H,N
MASS SPECTRUM
100
80
60
40
20
0.0
10
20
30
40
50
60
m/z
NIST Chemistry WebBook (https://webbook.nist.gov/chemistry)
Rel. Intensity
70
80](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F31e057a0-0cbc-4d2d-81a0-90ee88654c05%2F9e4b510f-44bc-426f-8371-9674935c768d%2Fzuma5mq_processed.jpeg&w=3840&q=75)
Transcribed Image Text:4) Contains C,H,N
MASS SPECTRUM
100
80
60
40
20
0.0
10
20
30
40
50
60
m/z
NIST Chemistry WebBook (https://webbook.nist.gov/chemistry)
Rel. Intensity
70
80
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